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Recycled and devulcanized rubber modified epoxy-based composites reinforced with nano-magnetic iron oxide, Fe_3O_4

机译:纳米磁性氧化铁Fe_3O_4增强的再生和脱硫橡胶改性环氧基复合材料

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摘要

Rubber modified epoxy based composites were designed by low cost production methods. Basically, clean and recycled materials were used to provide a solution for manufacturing of lightweight, cost efficient composites in industrial applications such as automotive and aeronautical engineering. In the present study four different compositions have been developed and characterized for their potential usage as structural materials. The matrix was prepared by treatment of epoxy with 10% recycled rubber. Nano-magnetic iron oxide, Fe3O4, was added to the matrix as reinforcement elements in different percentages. Nickel and aluminium were also add as auxiliary additional elements. Measurements of magnetic permeability and dielectrically properties have been carried out for electronic devise applications basically in aeronautical engineering. Dynamic Scanning Calorimeter (DSC) and Dynamic Mechanical Analysis (DMA) were carried out to determine thereto-mechanical properties. Static tests have been carried out by 3-point bending (3PB) tests for mechanical characterization. Furthermore, creep and wear behaviour of these compositions were evaluated by means of nanoindentation tests to analyze time dependent behaviour of these composites. Macro scratch tests were made in very high cycle test conditions for their measurements in long time resistance. Microstructural and fracture surface analyses have been carried out on the scanning electron microscopy (SEM).
机译:橡胶改性的环氧基复合材料是通过低成本生产方法设计的。基本上,使用清洁和可回收的材料为工业应用(例如汽车和航空工程)中的轻质,高性价比复合材料的制造提供解决方案。在本研究中,已开发出四种不同的组合物,并对其作为结构材料的潜在用途进行了表征。通过用10%的再生橡胶处理环氧树脂来制备基体。纳米磁性氧化铁Fe3O4以不同百分比添加到基体中作为增强元素。还添加了镍和铝作为辅助附加元素。基本上在航空工程中已经针对电子装置应用进行了磁导率和介电特性的测量。进行动态扫描量热仪(DSC)和动态力学分析(DMA)以确定其机械性能。静态测试已通过3点弯曲(3PB)测试进行了机械表征。此外,通过纳米压痕测试评估了这些组合物的蠕变和磨损行为,以分析这些复合材料的时间依赖性行为。宏划痕测试是在非常高的循环测试条件下进行的,以进行长时间电阻测试。在扫描电子显微镜(SEM)上进行了微结构和断裂表面分析。

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