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Treatment costs of ammonia recovery from biogas digestate by air stripping analyzed by process simulation

机译:通过工艺模拟分析通过气提从沼气消化液中回收氨的处理成本

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摘要

Ammonia can be recovered from liquid biogas digestate as ammonium sulfate by air stripping. A full-scale plant treating 30,000 kg h_(−1)of digestate was simulated in Aspen Plus.The classical sequence stripper–absorber was modified by introducing a flash drum to reduce the buffer capacity. The stripped digestate was mixed with NaOH up to a pH value of 9 and fed to the stripping column using air at 90 °C. The air flow rate was optimized considering the possible recycle from the absorption column. The complete process was modeled using the process simulator Aspen Plus considering a recovery of ammonia equal to 95%. The total capital investment was evaluated by means of Aspen Plus Process Economic Analyzer in about 5.5 million US$, and the costs of energy and chemicals were quantified in less than 1 million US$ year_(−1). A benefit of 1.6 US$ for m_(3)of digestate was obtained considering an ammonium sulfate price of 522 US$ ton_(−1).
机译:氨气可以通过气提从消化液中以硫酸铵形式回收。在Aspen Plus中模拟了处理30,000 kg h _(-1)消化物的大型工厂。通过引入闪蒸罐对经典的序列汽提吸收剂进行了改进,以减少缓冲能力。汽提后的消化物与NaOH混合至pH值为9,并使用90°C的空气进料至汽提塔。考虑到来自吸收塔的可能再循环,对空气流速进行了优化。考虑到氨的回收率等于95%,使用过程模拟器Aspen Plus对整个过程进行建模。通过Aspen Plus过程经济分析仪评估的总资本投资约为550万美元,而能源和化学品成本的量化值不到100万美元年(-1)。考虑到硫酸铵价格为522 US $ ton((-1),则m_(3)的消化物获得了1.6 US $的收益。

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