Sulfur-encapsulated zeolite micromotors for the selective removal of cesium from high-salt water with accelerated cleanup times

摘要

Bubble-propelled sulfur-encapsulated NaX zeolite (S-NaX) micromotors were developed for the selective removal of cesium from high-salt conditions with accelerated cleanup times. NaX was first modified with sulfur to provide additional Lewis acid-base interactions with Cs+ for enhanced Cs+ selectivity, and then Pt was half-deposited on S-NaX for bubble propulsion via the catalytic decomposition of H2O2. The average velocity of the resulting S-NaX/Pt micromotors in 5 wt% H2O2 is 39.7 +/- 17.1 mu m/s, which is higher than that of a previously reported Cs adsorbent micromotor (35.4 mu m/s). The Cs+ ion-exchange kinetics of the S-NaX micromotor is 1.32 times higher than that of the NaX micromotor in a 5 wt% H2O2 solution where the molar ratio of Na+ to Cs+ is 200, even though the sulfur in the S-NaX micromotor causes an adverse effect on the propulsion speed due to the sulfur poisoning effect. Moreover, the S-NaX micromotor in simulated groundwater also exhibited excellent Cs+ removal performance with distribution coefficient (K-d) values at least 3.2 times higher than those of the nonpropelled S-NaX and NaX micro-motor, demonstrating the great potential for the treatment of radioactive Cs+-contaminated water. (C) 2021 Elsevier Ltd. All rights reserved.