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Synthesis of nanoscale zero-valent iron/ordered mesoporous carbon for adsorption and synergistic reduction of nitrobenzene

机译:纳米零价铁/有序介孔碳的合成用于硝基苯的吸附和协同还原

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摘要

Nanoscale zero-valent iron (NZVI) supported on ordered mesoporous carbon (OMC) was synthesized through liquid phase reduction route. The NZVI/OMC composite was characterized by X-ray diffraction, N_2 adsorption/desorption and transmission electron microscopy. Results reveal that the composite possesses ordered mesostructure with NZVI distributing homogeneously on the surface of OMC support. The removal effects of nitrobenzene (NB) in water with OMC, NZVI/OMC and non-supported NZVI were evaluated. Results indicate that NZVI/OMC shows enhanced removal efficiency, which is attributed to its adsorption and synergistic reduction for NB. The transformation process of NB was further investigated by HPLC. Nitrosobenzene and phenylhydroxylamine were detected as intermediate products and aniline was the final reductive product.
机译:通过液相还原法合成了有序介孔碳(OMC)负载的纳米零价铁(NZVI)。通过X射线衍射,N_2吸附/解吸和透射电子显微镜对NZVI / OMC复合材料进行了表征。结果表明,该复合材料具有有序的介孔结构,NZVI均匀分布在OMC载体的表面。评估了OMC,NZVI / OMC和不支持的NZVI对水中硝基苯(NB)的去除效果。结果表明,NZVI / OMC的去除效率更高,这归因于其对NB的吸附和协同还原作用。通过HPLC进一步研究了NB的转化过程。检测到亚硝基苯和苯羟胺为中间产物,苯胺为最终还原产物。

著录项

  • 来源
    《Chemosphere》 |2012年第6期|p.655-660|共6页
  • 作者单位

    Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering,Nanjing University of Science and Technology,Nanjing 210094, PR China;

    Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering,Nanjing University of Science and Technology,Nanjing 210094, PR China;

    Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering,Nanjing University of Science and Technology,Nanjing 210094, PR China;

    Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering,Nanjing University of Science and Technology,Nanjing 210094, PR China;

    Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering,Nanjing University of Science and Technology,Nanjing 210094, PR China;

    Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering,Nanjing University of Science and Technology,Nanjing 210094, PR China;

    Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering,Nanjing University of Science and Technology,Nanjing 210094, PR China;

    Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering,Nanjing University of Science and Technology,Nanjing 210094, PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    nanoscale zero-valent iron; ordered mesoporous carbon; nitrobenzene; adsorption; reduction;

    机译:纳米零价铁;有序介孔碳硝基苯吸附减少;

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