Water contamination with heavy metals and trace elements from Kilembe copper mine and tailing sites in Western Uganda; implications for domestic water quality

摘要

The mining and processing of copper in Kilembe, Western Uganda, from 1956 to 1982 left over 15 Mt of cupriferous and cobaltiferous pyrite dumped within a mountain river valley, in addition to mine water which is pumped to the land surface. This study was conducted to assess the sources and concentrations of heavy metals and trace elements in Kilembe mine catchment water. Multi-element analysis of trace elements from point sources and sinks was conducted which included mine tailings, mine water, mine leachate, Nyamwamba River water, public water sources and domestic water samples using ICP-MS. The study found that mean concentrations (mg kg(-1)) of Co (112), Cu (3320), Ni (131), As (8.6) in mine tailings were significantly higher than world average crust and were being eroded and discharged into water bodies within the catchment. Underground mine water and leachate contained higher mean concentrations (mu g L-1) of Cu (9470), Co (3430) and Ni (590) compared with background concentrations (mu g L-1) in un contaminated water of 1.9, 0.21 and 0.67 for Cu, Co and Ni respectively. Over 25% of household water samples exceeded UK drinking water thresholds for Al of 200 mu g L-1, Co exceeded Winsconsin (USA drinking) water thresholds of 40 mu g L-1 in 40% of samples while Fe in 42% of samples exceeded UK thresholds of 200 mu g L-1. The study however found that besides mining activities, natural processes of geological weathering also contributed to Al, Fe, and Mn water contamination in a number of public water sources. (C) 2016 Elsevier Ltd. All rights reserved.