Characterization of polycyclic aromatic hydrocarbons in urban-rural integration area soil, North China: Spatial distribution, sources and potential human health risk assessment

摘要

The promotion of urbanization has accelerated the development of small manufacturing workshops and brought serious environmental problems. In this study, spatial distribution, sources and potential health risk for polycyclic aromatic hydrocarbons (PAHs) in urban-rural integration area soil in North China (800 km(2)) were discussed. The average total concentration of 16 PAHs was 225 mu g kg(-1), and range from 25 to 15155 mu g kg(-1) (n = 250). According to the European soil quality standards, more than 70% of the samples don't reach the pollution level, while around the small workshop concentration area and nonferrous metal smelter were more contaminated than other area. The spatial distribution of soil PAHs concentration shows that low molecular weight, medium molecular weight and high molecular weight is very similar to the distribution of total PAHs, indicating that is likely to be caused by point source pollution. The sources of PAHs were identified by positive matrix factorization. The main six sources in the region are coal and biomass combustion, creosote, coke tar, vehicle and oil, which is consistent with the local energy consumption structure. Finally, a deterministic assessment of the cancer risk showed that the range for children was 5.94 x 10(-8) to 2.53 x 10(-5), and adults it ranged from 2.11 x 10(-8) to 9.01 x 10(-6). There is not a carcinogenic risk value greater than 10(-4) in the entire region, but potential carcinogenic risks persisted in some areas. We conclude that PAHs pollution of soil in the area is an issue that deserves urgent attention for the relevant departments. (C) 2019 Elsevier Ltd. All rights reserved.