Hg(OTf)<sub>2</sub>–BINAPHANE-Catalyzed Enantioselective Anilino Sulfonamide Allyl Alcohol Cyclization

Dr. Hirofumi Yamamoto; Elisabeth Ho; Dr. Kosuke Namba; Dr. Hiroshi Imagawa; Prof. Dr. Mugio Nishizawa

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Hg(OTf)₂–BINAPHANE-Catalyzed Enantioselective Anilino Sulfonamide Allyl Alcohol Cyclization

机译：Hg（OTf）_{2 -联萘烷催化的对映选择性苯胺磺酰胺烯丙基醇环化反应}

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Chiral ligands: Hg(OTf)₂-catalyzed cyclization of anilino sulfonamide allyl alcohol is described; this reaction gives 2-vinyl indoline derivatives in good yields and excellent enantioselectivity by using a chiral BINAPHANE ligand (see scheme).

机译：手性配体：描述了Hg（OTf）_{2 催化苯胺磺酰胺烯丙醇的环化反应；通过使用手性BINAPHANE配体，该反应以良好的收率和优异的对映选择性得到2-乙烯基二氢吲哚衍生物（参见方案）。}

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来源
《Chemistry - A European Journal》 |2010年第37期|p.11271-11274|共4页
作者
Dr. Hirofumi Yamamoto; Elisabeth Ho; Dr. Kosuke Namba; Dr. Hiroshi Imagawa; Prof. Dr. Mugio Nishizawa;
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作者单位

Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514 (Japan), Fax: (+81)

88-655-3051;

Division of Chemistry, Hokkaido University, Kita-ku, Sapporo 060-0810 (Japan), Fax: (+81) 11-706-2703;

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正文语种 eng
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关键词
alcohols; allylic compounds; cyclization; enantioselectivity; mercury;

机译：醇;烯丙基化合物;环化;对映选择性;汞;

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专利

1. Hg(OTf)_2-BINAPHANE-catalyzed enantioselective anilino sulfonamide allyl alcohol cyclization [J] . Yamamoto H., Ho E., Namba K., Chemistry: A European journal . 2010,第37期

机译：Hg（OTf）_2-联胺催化的对映选择性苯胺磺酰胺烯丙醇环化
2. Hg(OTf)(2)-catalyzed cyclization of N-tosylanilinoallylic alcohols to 2-vinylindolines [J] . Namba K, Nakagawa Y, Yamamoto H, Synlett . 2008,第11期

机译：Hg（OTf）（2）催化的N-甲苯磺酸烯丙基醇成环化成2-vinylindolines
3. Cinchona Alkaloid/TiIV-Catalyzed Enantioselective Enamine–Trifluoropyruvate Condensation–Cyclization Reaction and Its Application to Drug-like Heterocycles [J] . Shinichi Ogawa, Norihito Iida, Etsuko Tokunaga, Chemistry - A European Journal . 2010,第24期

机译：金鸡纳生物碱/ Ti IV 催化的对映选择性烯胺-三氟丙酮酸缩合-环化反应及其在类药物杂环中的应用
4. Effective Hydroalkoxylation/Cyclization of Alkynyl Alcohol Catalyzed by ln(OTf)_3 [C] . ZHANG Jian-Ting, ZHU Cheng-Lin, FENG Jun-Min International Conference on Chemical Engineering and Advanced Materials . 2014

机译：用LN（OTF）_3催化催化的炔基醇的有效的水烷氧基化/环化
5. Cobalt Oxazoline Palladacycle (COP)-Catalyzed Enantioselective Formation of Branched Allylic C-O Bonds using Prochiral (E)-Allylic Alcohol Derivatives [D] . Olson, Angela Christine 2011

机译：使用前手性（E）-丙醇衍生物，钴恶唑啉丙二环（COP）催化支链烯丙基C-O键的对映选择性形成
6. Toward Palau’amine: Hg(OTf)2-Catalyzed Allyl Alcohol Cyclization of Acylhydrazide to Construct the Cyclopentane Core [O] . Kosuke Namba, Yukari Kaihara, Hirofumi Yamamoto, -1

机译：向帕劳的酰胺：Hg（OTF）2催化酰肼的烯丙基醇环化以构建环戊烷核心
7. Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate [O] . In Su Kim, Ming-Yu Ngai, Michael J. Krische 2008

机译：使用烯丙基乙酸酯作为烯丙基金属替代物，从醇或醛氧化水平的对糖尿病或醛氧化水平的酶催化羰基烯丙胺

Hg(OTf)2–BINAPHANE-Catalyzed Enantioselective Anilino Sulfonamide Allyl Alcohol Cyclization

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Hg(OTf)₂–BINAPHANE-Catalyzed Enantioselective Anilino Sulfonamide Allyl Alcohol Cyclization