Redox Reaction of the Pd0 Complex Bearing the Trost Ligand with meso-Cycloalkene-1,4-biscarbonates Leading to a Diamidato PdII Complex and 1,3-Cycloalkadienes: Enantioselective Desymmetrization Versus Catalyst Deactivation

Vasily N. Tsarev Dr. Dennis Wolters Dipl.-Chem. Hans-Joachim Gais Prof. Dr.

首页> 外文期刊>Chemistry - A European Journal >Redox Reaction of the Pd0 Complex Bearing the Trost Ligand with meso-Cycloalkene-1,4-biscarbonates Leading to a Diamidato PdII Complex and 1,3-Cycloalkadienes: Enantioselective Desymmetrization Versus Catalyst Deactivation

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Redox Reaction of the Pd0 Complex Bearing the Trost Ligand with meso-Cycloalkene-1,4-biscarbonates Leading to a Diamidato PdII Complex and 1,3-Cycloalkadienes: Enantioselective Desymmetrization Versus Catalyst Deactivation

机译：带有Trost配体的Pd 0 配合物与内-环烯-1,4-碳酸氢盐的氧化还原反应导致二Dia Pd II 配合物和1,3-环链二烯：对映选择性去对称化与催化剂失活

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来源
《Chemistry - A European Journal》 |2010年第9期|p.1-12|共12页
作者
Vasily N. Tsarev Dr. Dennis Wolters Dipl.-Chem. Hans-Joachim Gais Prof. Dr.;
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正文语种 eng
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关键词
alkylation; oxidation; palladium; redox chemistry; Trost ligand;

机译：烷基化;氧化;钯;氧化还原化学;Trost配体;

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1. Redox Reaction of the Pd-0 Complex Bearing the Trost Ligand with meso-Cycloalkene-1,4-biscarbonates Leading to a Diamidato Pd-II Complex and 1,3-Cycloalkadienes: Enantioselective Desymmetrization Versus Catalyst Deactivation [J] . Tsarev VN, Wolters D, Gais HJ Chemistry: A European journal . 2010,第9期

机译：带有Trost配体的Pd-0配合物与内-环烯烃-1,4-双碳酸酯的氧化还原反应导致Diamidato Pd-II配合物和1,3-环烷二烯：对映选择性脱对称与催化剂失活
2. Chiral 2,6-Bis(oxazolinyl)pyridine-Rare Earth Metal Complexes as Catalysts for Highly Enantioselective 1,3-Dipolar Cycloaddition Reactions of 2-Benzopyrylium-4-olates [J] . Hiroyuki Suga, Kei Inoue, Shuichi Inoue, The Journal of Organic Chemistry . 2005,第1期

机译：手性2,6-双（恶唑啉基）吡啶-稀土金属配合物作为2-苯并吡啶-4-油酸酯的高对映选择性1,3-偶极环加成反应的催化剂
3. Synthesis and Redox Behavior of 1,3-Bis(methylthio-) and 1,3-Bis(phenylthio)azulenes Bearing 2- and 3-Thienyl Substituents by Palladium-Catalyzed Cross-Coupling Reaction of 2- and 6-Haloazulenes with Thienylmagnesium Ate Complexes [J] . Shoji T, Ito S, Toyota K, European journal of organic chemistry . 2009,第25期

机译：钯催化2-和6-卤氮杂唑与噻吩基镁盐的交叉偶联反应，合成带有2-和3-噻吩基取代基的1,3-双（甲硫基）和1,3-双（苯硫基）氮杂复合体
4. Enantioselective Reactions of Bicyclic Allylic Compounds Based on Desymmetrization of a Symmetrical Allylic Ligand Using Chiral Palladium Complexes. [C] . Ryohei Ogawa, Yusuke Shigemori, Koichi Uehara Symposium on Organometallic Chemistry . 2006

机译：双环烯丙基化合物基于使用手性钯配合物的对称烯丙基配体的脱水化合物的映选择性反应。
5. Synthesis of PdII Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions [O] . Christopher C. Scarborough, Ana Bergant, Graham T. Sazama, -1

机译：含有对映体分辨的七元正杂环碳酸丁配体的PDII复合物的合成及其在不对称瓦克式氧化环化反应中使用的初始研究
6. Synthesis of PdII complexes bearing an enantiomerically resolved seven-membered N-heterocyclic carbene ligand and initial studies of their use in asymmetric Wacker-type oxidative cyclization reactions [O] . Christopher C. Scarborough, Ana Bergant, Graham T. Sazama, 2009

机译：含有对映体分辨的七元氮杂环碳配体的PDII复合物的合成及其在不对称瓦克式氧化环化反应中使用的初始研究

Redox Reaction of the Pd0 Complex Bearing the Trost Ligand with meso-Cycloalkene-1,4-biscarbonates Leading to a Diamidato PdII Complex and 1,3-Cycloalkadienes: Enantioselective Desymmetrization Versus Catalyst Deactivation

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