A new enantiopure unsaturated dicarboxylate as a 4-connected unit in a flexible homochiral PtS-type framework

摘要

Metal cation mediated chiral ligand transformation of (S)-camphanic acid leads to a new enantiopure unsaturated dicarboxylate that links tetrahedral Zn~(2+) sites into 3-D homochiral 4-connected PtS-type framework structures, Zn(tced) (1, H_2tced = 1,2,2-