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A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

机译:近似于长方体的四壳,136金属3d-4f杂金属簇

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摘要

A nanosized heterometallic cluster containing 60 La(III) and 76 Ni(I) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO_3)_3-Ni(NO_3)_2 system using iminodiacetate as an ancillary ligand to control the hydrolysis.
机译:通过混合La(NO_3)_3-Ni()的水解反应获得了包含60个La(III)和76个Ni(I)离子的纳米级杂金属簇,这些离子排列成四层巢状骨架结构。 NO_3)_2系统使用亚氨基二乙酸酯作为辅助配体来控制水解。

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  • 来源
    《Chemical Communications》 |2009年第29期|354-356|共3页
  • 作者单位

    State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China Department of Chemistry, University of Arizona, Tucson, Arizona 85721, USA;

    State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China;

    Department of Chemistry, University of California, Berkeley, CA 94720-1460, USA;

    State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China Department of Chemistry, University of Arizona, Tucson, Arizona 85721, USA;

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  • 入库时间 2022-08-17 13:25:47

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