[LnNa(PhCO_2)_4] (Ln = Ho, Dy): the first examples of chiral srs 3D networks constructed using the monotopic benzoate ligand

Zeeshan Majeed; Kartik C. Mondal; George E. Kostakis; Yanhua Lan; Christopher E. Anson; Annie K. Powell

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[LnNa(PhCO_2)_4] (Ln = Ho, Dy): the first examples of chiral srs 3D networks constructed using the monotopic benzoate ligand

机译：[LnNa（PhCO_2）_4]（Ln = Ho，Dy）：使用单端苯甲酸酯配体构建的手性srs 3D网络的第一个示例

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We present the surprising result that the combination of the monotopic benzoate ligand with lanthanide ions leads to a 3D network which also possesses the chiral srs-topology.

机译：我们提出了令人惊讶的结果，即单价苯甲酸酯配体与镧系元素离子的组合导致3D网络，该网络也具有手性srs拓扑结构。

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来源
《Chemical Communications》 |2010年第15期|p.2551-2553|共3页
作者
Zeeshan Majeed; Kartik C. Mondal; George E. Kostakis; Yanhua Lan; Christopher E. Anson; Annie K. Powell;
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Institut fuer Anorganische Chemie, Karlsruhe Institute of Technology, Engessertsr. 15, D-76131 Karlsruhe, Germany;

Institut fuer Anorganische Chemie, Karlsruhe Institute of Technology, Engessertsr. 15, D-76131 Karlsruhe, Germany;

Institut fuer Nanotechnologie, Karlsruhe Institute of Technology,Postfach 3640, D-76021 Karlsruhe, Germany;

Institut fuer Anorganische Chemie, Karlsruhe Institute of Technology, Engessertsr. 15, D-76131 Karlsruhe, Germany;

Institut fuer Anorganische Chemie, Karlsruhe Institute of Technology, Engessertsr. 15, D-76131 Karlsruhe, Germany;

Institut fuer Anorganische Chemie, Karlsruhe Institute of Technology, Engessertsr. 15, D-76131 Karlsruhe, Germany Institut fuer Nanotechnologie, Karlsruhe Institute of Technology,Postfach 3640, D-76021 Karlsruhe, Germany;

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1. Efficient synthesis of manganese(II) carboxylates: from a trinuclear cluster [Mn_3(PhCO_2)_6(THF)_4] to a unique [Mn(PhCO_2)_2]_n chiral 3D network [J] . Arkadiusz Kornowicz, Szymon Komorski, Zbigniew Wróbel, Dalton transactions: An international journal of inorganic chemistry . 2014,第8期

机译：有效合成羧酸锰（II）：从三核簇[Mn_3（PhCO_2）_6（THF）_4]到独特的[Mn（PhCO_2）_2] _n手性3D网络
2. Efficient synthesis of manganese(II) carboxylates: from a trinuclear cluster [Mn_3(PhCO_2)_6(THF)_4] to a unique [Mn(PhCO_2)_2]_n chiral 3D network [J] . Arkadiusz Kornowicz, Szymon Komorski, Zbigniew Wróbel, Dalton transactions: An international journal of inorganic chemistry . 2014,第8期

机译：有效合成羧酸锰（II）：从三核簇[Mn_3（PhCO_2）_6（THF）_4]到独特的[Mn（PhCO_2）_2] _n手性3D网络
3. Assembly of heterobimetallic Ni~(II)-Ln~(III) (Ln~(III) = Dy~(III), Tb~(III), Gd~(III), Ho~(III), Er~(III), Y~(III)) complexes using a ferrocene ligand: slow relaxation of the magnetization in Dy~(III), Tb~(III) and Ho~(III) analogues [J] . Amit Chakraborty, Prasenjit Bag, Eric Rivière, Dalton transactions: An international journal of inorganic chemistry . 2014,第23期

机译：异双金属Ni〜（II）-Ln〜（III）的组装（Ln〜（III）= Dy〜（III），Tb〜（III），Gd〜（III），Ho〜（III），Er〜（III）二茂铁配体形成的Y，（Y〜（III））配合物：Dy〜（III），Tb〜（III）和Ho〜（III）类似物中磁化的缓慢弛豫
4. Acentric phase formation in AgLnX, (Ln #x003D; Dy, Ho, Er; X #x003D; S, Se, Te) compounds [C] . {missing} IEEE Russia School and Seminar on Fundamental Problems of Micro/Nanosystems Technologies . 2010

机译：Aglnx中的缩高相形成，（ln = dy，ho，er; x = s，se，te）化合物
5. Inaugural Article: Ba2LnSbO6 and Sr2LnSbO6 (Ln =Dy Ho Gd) double perovskites: Lanthanides in the geometrically frustratingfcc lattice [O] . H. Karunadasa, Q. Huang, B. G. Ueland, 2003

机译：开幕文章：Ba2LnSbO6和Sr2LnSbO6（Ln =DyHoGd）双钙钛矿：镧系元素在几何上令人沮丧fcc晶格
6. Ba2LnSbO6 and Sr2LnSbO6 (Ln = Dy, Ho, Gd) double perovskites: Lanthanides in the geometrically frustrating fcc lattice [O] . Karunadasa, H., Huang, Q., Ueland, B. G., 2003

机译：Ba2LnSbO6和Sr2LnSbO6（Ln = Dy，Ho，Gd）双钙钛矿：镧系元素在几何上令人沮丧 fcc晶格

[LnNa(PhCO_2)_4] (Ln = Ho, Dy): the first examples of chiral srs 3D networks constructed using the monotopic benzoate ligand

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