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An unusual case of symmetry-preserving isomerism

机译:保留对称性的不寻常情况

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摘要

Two isomeric phases of the NbO-type structure have been discovered: PCN-16 (α phase) and PCN-16' (β phase), and gas sorption studies revealed that the α phase possesses a larger surface area, leading to higher hydrogen and methane storage capacity as compared with the β phase.
机译:已发现NbO型结构的两个异构相:PCN-16(α相)和PCN-16'(β相),并且气体吸附研究表明,α相具有较大的表面积,从而导致较高的氢和与β相相比,甲烷的储气量

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  • 来源
    《Chemical Communications》 |2010年第8期|1329-1331|共3页
  • 作者单位

    Department of Chemistry, Texas A&M University, PO Box 30012,College Station, TX 77842, USA;

    Chemical Sciences and Engineering Division,Argonne National Laboratory, 9700 S. Cass Avenue, Argonne,IL 60439, USA;

    NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8562, USA;

    Department of Chemistry, Texas A&M University, PO Box 30012,College Station, TX 77842, USA;

    Department of Chemistry, Texas A&M University, PO Box 30012,College Station, TX 77842, USA;

    Department of Chemistry, Texas A&M University, PO Box 30012,College Station, TX 77842, USA;

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  • 入库时间 2022-08-17 13:23:35

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