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Selective oxidation of terminal aryl and aliphatic alkenes to aldehydes catalyzed by iron(III) porphyrins with triflate as a counter anion

机译:铁(III)卟啉以三氟甲磺酸盐为抗衡阴离子将末端芳基和脂族烯烃选择性氧化为醛

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摘要

[Fe(Por)CF_3SO_3] (Por = porphyrin dianion) can efficiently catalyze selective oxidation of terminal aryl alkenes and aliphatic alkenes to aldehydes in good to high yields under mild conditions.
机译:[Fe(Por)CF_3SO_3](Por =卟啉二价阴离子)可以在温和的条件下以良好或高收率有效地催化末端芳基烯烃和脂族烯烃选择性氧化为醛。

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  • 来源
    《Chemical Communications》 |2011年第39期|p.10963-10965|共3页
  • 作者单位

    Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis,Shanghai Institute of Organic Chemistry, 354 Feng Lin Road,Shanghai, China;

    Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis,Shanghai Institute of Organic Chemistry, 354 Feng Lin Road,Shanghai, China;

    Department of Chemistry, State Key Laboratory of Synthetic Chemistry, and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis,The University of Hong Kong, Pokfulam Road, Hong Kong, China;

    Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis,Shanghai Institute of Organic Chemistry, 354 Feng Lin Road,Shanghai, China,Department of Chemistry, State Key Laboratory of Synthetic Chemistry, and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis,The University of Hong Kong, Pokfulam Road, Hong Kong, China;

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  • 入库时间 2022-08-17 13:22:46

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