Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

Bryan Carlson; Adelia J. A. Aquino; Louisa J. Hope-Weeks; Bruce Whittlesey; Brian McNerney; William L. Hase; Clemens Krempner

首页> 外文期刊>Chemical Communications >Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

【24h】

Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

机译：碱土金属的均三（甲氧基二甲基甲硅烷基）硅烷基化物：首先是带有两个裸甲硅烷基阴离子的两性离子硅烷基化物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The first zwitterionic alkaline earth metal silanides featuring two naked silyl anions were synthesized and a combined structural and computational study on these zwitterions revealed a correlation between the energy of the HOMO and the degree of negative charge of the naked silyl anions.

机译：合成了具有两个裸甲硅烷基阴离子的首个两性离子碱土金属硅化物，对这些两性离子进行的组合结构和计算研究表明，HOMO的能量与裸甲硅烷基阴离子的负电荷程度之间具有相关性。

著录项

来源
《Chemical Communications》 |2011年第39期|p.11089-11091|共3页
作者
Bryan Carlson; Adelia J. A. Aquino; Louisa J. Hope-Weeks; Bruce Whittlesey; Brian McNerney; William L. Hase; Clemens Krempner;
展开▼
作者单位

Department of Chemistry and Biochemistry, Texas Tech University,Memorial Dr & Boston, Lubbock, TX, 79409, USA;

Department of Chemistry and Biochemistry, Texas Tech University,Memorial Dr & Boston, Lubbock, TX, 79409, USA;

Department of Chemistry and Biochemistry, Texas Tech University,Memorial Dr & Boston, Lubbock, TX, 79409, USA;

Department of Chemistry and Biochemistry, Texas Tech University,Memorial Dr & Boston, Lubbock, TX, 79409, USA;

Department of Chemistry and Biochemistry, Texas Tech University,Memorial Dr & Boston, Lubbock, TX, 79409, USA;

Department of Chemistry and Biochemistry, Texas Tech University,Memorial Dr & Boston, Lubbock, TX, 79409, USA;

Department of Chemistry and Biochemistry, Texas Tech University,Memorial Dr & Boston, Lubbock, TX, 79409, USA;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
入库时间 2022-08-17 13:22:50

相似文献

外文文献
中文文献
专利

1. Syntheses and Structures of the First Heavy Alkaline Earth Metal Bis(tris(trimethylsilyl))silanides [J] . Weijie Teng, Karin Ruhlandt-Senge Organometallics . 2004,第11期

机译：第一重碱土金属双（三（三甲基甲硅烷基））硅烷的合成与结构
2. A supramolecular approach to zwitterionic alkaline metal silanides and formation of heterobimetallic silanidesf [J] . Hui Li, Louisa J. Hope-Weeks, Clemens Krempner Chemical Communications . 2011,第14期

机译：两性离子碱金属硅化物的超分子方法和杂双金属硅化物的形成f
3. The Tris(pentafluoroethyl)silanide Anion [J] . Schwarze Nico, Steinhauer Simon, Neumann Beate, Angewandte Chemie . 2016,第52期

机译：三（五氟乙基）硅烷基阴离子
4. Coke-free Ni catalyst promoted by small amount of alkaline and alkaline earth metals in CO2 reforming of CH4 [C] . 侯昭胤, 横田修, 田中琢実石油学会年会 . 2002

机译：通过CH4的CO2重整中少量碱性和碱土金属促进的可焦炭Ni催化剂
5. Synthesis and reactivity of tungsten tris-(tri-tertbutyl) silyl imido complexes: Neutral and anionic derivatives, indirect evidence for the intermediacy of metal-alkane complexes in solution [D] . Schafer, Daniel Francis, II 1999

机译：钨三-（三叔丁基）甲硅烷基亚氨基配合物的合成和反应性：中性和阴离子衍生物，溶液中金属-烷烃配合物的间接证据
6. Electronic nature of zwitterionic alkali metal methanides silanides and germanides – a combined experimental and computational approach [O] . H. Li, A. J. A. Aquino, D. B. Cordes, 2017

机译：两性离子碱金属甲烷化物硅烷和锗化物的电子性质–实验和计算相结合的方法
7. Syntheses and Structures of the First Heavy Alkaline Earth Metal Bis(tris(trimethylsilyl))silanides [O] . -1

机译：第一重型碱土金属双（Tris（三甲基甲硅烷基））硅烷化的合成和结构
8. Reactions of Carbon Monoxide with Trimethylsilyl and Tris(trimethylsilyl)silyl Derivatives of Group 4 Metals. Synthesis, Characterization, and Reactivity of Silaacyl Complexes [R] . Campion, B. K., Falk, J., Tilley, T. D. 1987

机译：一氧化碳与第3族金属的三甲基甲硅烷基和三（三甲基甲硅烷基）甲硅烷基衍生物的反应。 silaacyl配合物的合成，表征和反应性

Homoleptic tris(methoxydimethylsilyl)silanides of the alkaline earth metals: first zwitterionic silanides with two naked silyl anions

摘要

著录项

相似文献

相关主题

期刊订阅