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High reaction activity of nitrogen-doped carbon nanotubes toward the electrooxidation of nitric oxide

机译:氮掺杂碳纳米管对一氧化氮的电氧化的高反应活性

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摘要

Carbon nanotubes doped with N (NCNTs) enable 1.5 times faster electron-transfer kinetics for the oxidation of NO compared to pristine carbon nanotubes (CNTs), which may be due to the low adsorption energy for a NO on pyridinic NCNT(5,5) allowing NO to lose electrons readily and facilitate the following oxidation to nitrate.
机译:掺杂N的碳纳米管(NCNT)使得NO氧化的电子传递动力学比原始碳纳米管(CNT)快1.5倍,这可能是由于吡啶在NCNT上对NO的吸附能低(5,5)使NO容易失去电子,并促进随后的氧化成硝酸盐。

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  • 来源
    《Chemical Communications》 |2011年第25期|p.7137-7139|共3页
  • 作者单位

    School of Chemistry and Chemical Engineering, Southeast University Jiangning, Nanjing 211189, People's Republic of China;

    Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;

    Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;

    Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;

    School of Chemistry and Chemical Engineering, Southeast University Jiangning, Nanjing 211189, People's Republic of China;

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