Enhanced photooxidation sensitizers: the first examples of cyclometalated pyrene complexes of iridium(Ⅲ)

Andrew J. Hallett; Nathan White; Wanhua Wu; Xiaoneng Cui; Peter N. Horton; Simon J. Coles; Jianzhang Zhao; Simon J. A. Pope

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Enhanced photooxidation sensitizers: the first examples of cyclometalated pyrene complexes of iridium(Ⅲ)

机译：增强型光氧化敏化剂：铱（Ⅲ）的环金属化ated配合物的第一例

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The iridium(Ⅲ) cyclometalation of alkylated pyrene-benzimidazole ligands proceeds in an unprecedented manner. The resultant complexes display remarkably enhanced photooxidation capabilities using 1,5-dihydroxynaphthalene as a substrate.

机译：烷基化pyr-苯并咪唑配体的铱（Ⅲ）环金属化以前所未有的方式进行。使用1，5-二羟基萘作为底物，所得复合物显示出显着增强的光氧化能力。

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《Chemical Communications》 |2012年第88期|p.10838-10840|共3页
作者
Andrew J. Hallett; Nathan White; Wanhua Wu; Xiaoneng Cui; Peter N. Horton; Simon J. Coles; Jianzhang Zhao; Simon J. A. Pope;
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School of Chemistry, Cardiff University, Wales, UK;

School of Chemistry, Cardiff University, Wales, UK;

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E208 West Campus, 2 Ling-Gong Road, Dalian 116012, P.R. China;

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E208 West Campus, 2 Ling-Gong Road, Dalian 116012, P.R. China;

UK National Crystallographic Service, Chemistry, Faculty of Natural and Environmental Sciences, University of Southampton, Highfield, Southampton, SO17 1BJ, England, UK;

UK National Crystallographic Service, Chemistry, Faculty of Natural and Environmental Sciences, University of Southampton, Highfield, Southampton, SO17 1BJ, England, UK;

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E208 West Campus, 2 Ling-Gong Road, Dalian 116012, P.R. China;

School of Chemistry, Cardiff University, Wales, UK;

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7. Enhanced photooxidation sensitizers: the first examples of cyclometalated pyrene complexes of iridium(iii) [O] . Hallett, Andrew Jon, White, Nathan, Wu, Wanhua, 2012

机译：增强型光氧化敏化剂：铱（iii）的环金属化pyr配合物的第一个实例

Enhanced photooxidation sensitizers: the first examples of cyclometalated pyrene complexes of iridium(Ⅲ)

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