Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(III)complexes with 2,3-quinoxalinediolate ligands

Julia Vallejo; Joan Cano; Isabel Castro; Miguel Julve; Francesc Lloret; Oscar Fabelo; Laura Canadillas-Delgado; Emilio Pardo

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Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(III)complexes with 2,3-quinoxalinediolate ligands

机译：碳酸盐桥联的2,3-喹喔啉二醇酯配体的双核镧系元素（III）络合物的慢磁弛豫

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The coordination chemistry of the 2,3-quinoxalinediolate ligand with different lanthanide(m) ions in basic media in air affords a new family of carbonato-bridged M_2~(III) compounds (M = Pr, Gd and Dy), the Dy_2~(III) analogue exhibiting slow magnetic relaxation behaviour typical of single-molecule magnets.

机译：在空气中的碱性介质中，2,3-喹喔啉二醇酸酯配体与不同的镧系元素（m）离子的配位化学提供了一个新的碳族桥联的M_2〜（III）化合物（M = Pr，Gd和Dy），即Dy_2〜（III）表现出单分子磁体特有的慢磁弛豫行为的类似物。

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来源
《Chemical Communications》 |2012年第62期|p.7726-7728|共3页
作者
Julia Vallejo; Joan Cano; Isabel Castro; Miguel Julve; Francesc Lloret; Oscar Fabelo; Laura Canadillas-Delgado; Emilio Pardo;
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作者单位

Departament de Quimica Inorgdnica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valencia, 46980 Paterna, Valencia, Spain;

Departament de Quimica Inorgdnica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valencia, 46980 Paterna, Valencia, Spain,Fundacio General de la Universitat de Valencia (FGUV), Universitat de Valencia, 46980 Paterna, Valencia, Spain;

Departament de Quimica Inorgdnica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valencia, 46980 Paterna, Valencia, Spain;

Departament de Quimica Inorgdnica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valencia, 46980 Paterna, Valencia, Spain;

Departament de Quimica Inorgdnica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valencia, 46980 Paterna, Valencia, Spain;

Instituto de Ciencia de Materiales de Aragon, CSIC-Universidad de Zaragoza, Zaragoza, 50009, Spain,Institut Laue Laneevin, Grenoble. 38042. France;

Instituto de Ciencia de Materiales de Aragon, CSIC-Universidad de Zaragoza, Zaragoza, 50009, Spain,Institut Laue Laneevin, Grenoble. 38042. France;

Departament de Quimica Inorgdnica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valencia, 46980 Paterna, Valencia, Spain;

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入库时间 2022-08-17 13:20:56

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Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(III)complexes with 2,3-quinoxalinediolate ligands

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