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Circular dichroism and circularly polarized luminescence triggered by self-assembly of tris(phenylisoxazolyl)benzenes possessing a perylenebisimide moiety

机译:由具有per双酰亚胺部分的三(苯基异恶唑基)苯自组装引发的圆二色性和圆偏振发光

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摘要

Chiral tris(phenylisoxazolyl)benzenes possessing a perylenebisimide moiety assembled to form helical stacks. The self-assembling behavior of the helical stacks responded to changes in solvent properties, temperature, and concentration. Strong circular dichroism (CD) and circularly polarized luminescence (CPL) of their assemblies were displayed, and were controlled by external stimuli.
机译:具有assembled联二酰亚胺部分的手性三(苯基异恶唑基)苯组装形成螺旋堆叠。螺旋堆叠的自组装行为响应于溶剂性质,温度和浓度的变化。展示了其组件的强圆二色性(CD)和圆偏振发光(CPL),并受外部刺激控制。

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  • 来源
    《Chemical Communications》 |2012年第48期|p.6025-6027|共3页
  • 作者单位

    Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan;

    Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan;

    Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan;

    Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, 630-0192, Japan;

    Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, 630-0192, Japan;

    Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, 630-0192, Japan;

    Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan;

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  • 入库时间 2022-08-17 13:20:51

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