Neutral copper-phosphido-borane complexes: synthesis, characterization, and use as precatalysts in C_(sp)-P bond formation

Ibrahim Abdellah; Elise Bernoud; Jean-Francois Lohier; Carole Alayrac; Loiec Toupet; Christine Lepetit; Annie-Claude Gaumont

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Neutral copper-phosphido-borane complexes: synthesis, characterization, and use as precatalysts in C_(sp)-P bond formation

机译：中性铜-磷-硼烷络合物：合成，表征，并用作C_（sp）-P键形成中的前催化剂

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Copper-phosphido-borane complexes were synthesized and isolated for the first time. Their structures were experimentally and computationally investigated. They were shown to display catalytic activity in C_(sp)-P bond formation.

机译：首次合成和分离了铜-磷酰基-硼烷配合物。他们的结构进行了实验和计算研究。它们显示出在C_（sp）-P键的形成中具有催化活性。

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《Chemical Communications》 |2012年第34期|p.4088-4090|共3页
作者
Ibrahim Abdellah; Elise Bernoud; Jean-Francois Lohier; Carole Alayrac; Loiec Toupet; Christine Lepetit; Annie-Claude Gaumont;
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Laboratoire de Chimie Moleculaire et Thio-organique, UMR CNRS 6507, INC3M, FR 3038, ENSICAEN & Universite de Caen, 6 boulevard du Marechal Juin, F-14050 Caen, France;

Laboratoire de Chimie Moleculaire et Thio-organique, UMR CNRS 6507, INC3M, FR 3038, ENSICAEN & Universite de Caen, 6 boulevard du Marechal Juin, F-14050 Caen, France;

Laboratoire de Chimie Moleculaire et Thio-organique, UMR CNRS 6507, INC3M, FR 3038, ENSICAEN & Universite de Caen, 6 boulevard du Marechal Juin, F-14050 Caen, France;

Laboratoire de Chimie Moleculaire et Thio-organique, UMR CNRS 6507, INC3M, FR 3038, ENSICAEN & Universite de Caen, 6 boulevard du Marechal Juin, F-14050 Caen, France;

Institut de Physique de Rennes, UMR CNRS 6251, Universite de Rennes 1, 263 avenue du General Leclerc, F-35042 Rennes, France;

CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, F-31077 Toulouse, France,Universite de Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France;

Laboratoire de Chimie Moleculaire et Thio-organique, UMR CNRS 6507, INC3M, FR 3038, ENSICAEN & Universite de Caen, 6 boulevard du Marechal Juin, F-14050 Caen, France;

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Neutral copper-phosphido-borane complexes: synthesis, characterization, and use as precatalysts in C_(sp)-P bond formation

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