Nickel-catalyzed [4 + 2] cycloaddition for highly substituted arenes

Hiroaki Horie; Takuya Kurahashi; Seijiro Matsubara

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Nickel-catalyzed [4 + 2] cycloaddition for highly substituted arenes

机译：镍催化的[4 + 2]环加成反应，用于高度取代的芳烃

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Nickel(O) catalyzed [4 + 2] cycloaddition of electron-deficient dienes to alkynes and subsequent aromatization gave highly substituted arenes. This formal inverse electron-demand Diels-Alder cycloaddition is attributed to the formation of a seven-membered nickelacycle from a diene and an alkyne.

机译：镍（O）催化电子不足的二烯与炔烃的[4 + 2]环加成反应，随后进行芳构化，得到高度取代的芳烃。这种形式上的反电子需求的Diels-Alder环加成反应归因于由二烯和炔烃形成的七元镍环。

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《Chemical Communications》 |2012年第32期|p.3866-3868|共3页
作者
Hiroaki Horie; Takuya Kurahashi; Seijiro Matsubara;
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Department of Material Chemistry, Graduate School of Engineering,Kyoto University, Kyoto 615-8510, Japan;

Department of Material Chemistry, Graduate School of Engineering,Kyoto University, Kyoto 615-8510, Japan;

Department of Material Chemistry, Graduate School of Engineering,Kyoto University, Kyoto 615-8510, Japan;

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入库时间 2022-08-17 13:20:27

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Nickel-catalyzed [4 + 2] cycloaddition for highly substituted arenes

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