首页> 外文期刊>Chemical Communications >Asymmetric [3 + 2] annulation of allenes with maleimides catalyzed by dipeptide-derived phosphines: facile creation of functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers
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Asymmetric [3 + 2] annulation of allenes with maleimides catalyzed by dipeptide-derived phosphines: facile creation of functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers

机译:二肽衍生的膦催化的具有马来酰亚胺的不对称[3 + 2]环烯基芳烃环化反应:轻松创建包含两个叔立体中心的功能化双环环戊烯

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摘要

D-Threonine-L-tert-leucine-derived bifunctional phosphine, Cat. 11, catalyzed highly enantioselective [3 + 2] annulation of maleimides with allenes has been disclosed, allowing the synthesis of optically active functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers in good to high yields along with good to high enantioselectivities.
机译:D-苏氨酸-L-叔亮氨酸衍生的双功能膦,目录号。参见图11,已经公开了马来酰亚胺与丙二烯的催化的高对映选择性[3 + 2]环合,其允许以良好至高收率以及良好至高对映选择性合成包含两个叔立体中心的光学活性官能化双环环戊烯。

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  • 来源
    《Chemical Communications》 |2012年第7期|p.970-972|共3页
  • 作者单位

    Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 MeiLong Road, Shanghai 200237, P. R. China;

    Department of Chemistry & Medicinal Chemistry Program, Life Sciences Institute, National University of Singapore, 3 Science Drive 3, Republic of Singapore 117543;

    State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. China;

    Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 MeiLong Road, Shanghai 200237, P. R. China,State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. China;

    Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 MeiLong Road, Shanghai 200237, P. R. China,Department of Chemistry & Medicinal Chemistry Program, Life Sciences Institute, National University of Singapore, 3 Science Drive 3, Republic of Singapore 117543;

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  • 入库时间 2022-08-17 13:20:12

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