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One-dimensional alignment of strong Lewis acid sites in a porous coordination polymer

机译:多孔配位聚合物中强路易斯酸位点的一维排列

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摘要

A new lanthanoid porous coordination polymer, La-BTTc (BTTc = benzene-1,3,5-tris(2-thiophene-5-carboxylate)), was synthesized and structurally characterized to have densely aligned one-dimensional open metal sites, which were found to act as strong Lewis acid sites after the removal of the coordinated solvent.
机译:合成了一种新的镧系元素多孔配位聚合物La-BTTc(BTTc =苯-1,3,5-三(2-噻吩-5-羧酸酯)),其结构特征是具有密集排列的一维开放金属位点,发现在除去配位溶剂后,它们被用作强路易斯酸位点。

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  • 来源
    《Chemical Communications》 |2013年第89期|10459-10461|共3页
  • 作者单位

    Advanced Materials Research Laboratory, Sumitomo Chemical Co., Ltd., 6 Kitahara, Tsukuba, Ibaraki 300-3294, Japan;

    Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida Ushinomiyacho, Sakyo-ku, Kyoto 606-8501, Japan;

    Advanced Materials Research Laboratory, Sumitomo Chemical Co., Ltd., 6 Kitahara, Tsukuba, Ibaraki 300-3294, Japan;

    Advanced Materials Research Laboratory, Sumitomo Chemical Co., Ltd., 6 Kitahara, Tsukuba, Ibaraki 300-3294, Japan;

    Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida Ushinomiyacho, Sakyo-ku, Kyoto 606-8501, Japan ,Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan;

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  • 入库时间 2022-08-17 13:18:50

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