Pd-Catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids

Jiang Ye; Jingming Zhao; Jing Xu; Yuxue Mao; Yong Jian Zhang

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Pd-Catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids

机译：钯催化的烯丙基醇与芳基硼酸的立体定向烯丙基-芳基偶联

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摘要

An efficient method for Pd-catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids has been described. The reactions proceeded smoothly in the presence of Pd_2(dba)_3 CHCI_3 and racemic BINAP under mild and neutral conditions, affording allyl-aryl coupling products in moderate to high yields with excellent stereospecificities.

机译：已经描述了用于Pd催化的烯丙基醇与芳基硼酸的立体特异性烯丙基-芳基偶联的有效方法。在温和和中性条件下，在Pd_2（dba）_3 CHCI_3和外消旋BINAP的存在下，反应平稳进行，从而以中等至高收率提供烯丙基-芳基偶联产物，并具有出色的立体特异性。

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《Chemical Communications》 |2013年第84期|9761-9763|共3页
作者
Jiang Ye; Jingming Zhao; Jing Xu; Yuxue Mao; Yong Jian Zhang;
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作者单位

School of Chemistry and Chemical Engineering, and Shanghai Key Laboratory of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University,800 Dongchuan Road, Shanghai 200240, P. R. China;

School of Chemistry and Chemical Engineering, and Shanghai Key Laboratory of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University,800 Dongchuan Road, Shanghai 200240, P. R. China;

School of Chemistry and Chemical Engineering, and Shanghai Key Laboratory of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University,800 Dongchuan Road, Shanghai 200240, P. R. China;

School of Chemistry and Chemical Engineering, and Shanghai Key Laboratory of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University,800 Dongchuan Road, Shanghai 200240, P. R. China;

School of Chemistry and Chemical Engineering, and Shanghai Key Laboratory of Electrical Insulation and Thermal Aging, Shanghai Jiao Tong University,800 Dongchuan Road, Shanghai 200240, P. R. China;

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入库时间 2022-08-17 13:18:45

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2. Palladium-Catalyzed γ-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids [J] . Hirohisa Ohmiya, Yusuke Makida, Dong Li, Journal of the American Chemical Society . 2010,第2期

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Pd-Catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids

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