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Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides

机译：铜催化炔丙基卤化物的亲核三氟甲基化

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摘要

Reactions of propargylic halides with trifluoromethyltrimethyl-silane in the presence of a catalytic amount of copper(Ⅰ) thiophene-2-carboxylate (CuTC) have been found to give the corresponding trifluoromethylated products in good to high yields with a high selectivity.
机译：已发现炔丙基卤与三氟甲基三甲基硅烷在催化量的噻吩-2-羧酸铜（Ⅰ）存在下反应，可以高产率，高选择性地得到相应的三氟甲基化产物。

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  • 来源
    《Chemical Communications》 |2013年第71期|7809-7811|共3页
  • 作者

    Yoshihiro Miyake; Shin-ichi Ota; Masashi Shibata; Kazunari Nakajima; Yoshiaki Nishibayashi;

  • 作者单位

    Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan;

    Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan;

    Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan;

    Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan;

    Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan;

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  • 入库时间 2022-08-17 13:18:35

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