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Palladium-catalyzed para-selective arylation of phenols with aryl iodides in water

机译：钯在水中的苯酚与芳基碘化物的对位选择性芳基化

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摘要

Highly para-selective palladium-catalyzed direct arylation of phenols with aryl iodides was demonstrated by taking advantage of the formal inverse direct arylation strategy, A series of 4-aryl phenols were synthesised by employing water as a "green" solvent under mild reaction conditions.
机译：利用形式逆直接芳基化策略，证明了苯酚与芳基碘的高度对选择性钯催化的直接芳基化。在温和的反应条件下，以水为“绿色”溶剂，合成了一系列4-芳基苯酚。

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  • 来源
    《Chemical Communications》 |2013年第69期|7653-7655|共3页
  • 作者

    Zhiqing Wu; Feihua Luo; Si Chen; Zhengkai Li; Haifeng Xiang; Xiangge Zhou;

  • 作者单位

    Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China;

    Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China;

    Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China;

    Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China;

    Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China;

    Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China,Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China;

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