Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)_2

Mario Janjetovic; Annika M.Traeff; Tobias Ankner; Jenny Wettergren; Goeran Hilmersson

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Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)_2

机译：使用Sm（HMDS）_2的脂族C-F键的溶剂依赖性还原脱氟

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Sm(HMDS)_2 in n-hexane mediates fast cleavage of primary, secondary and tertiary alkyl fluorides in good to excellent yields.In n-hexane Sm(HMDS)_2 exhibits uniquely enhanced reductive ability towards the C-F bond compared to when using THF as solvent.

机译：正己烷中的Sm（HMDS）_2介导伯，仲和叔烷基氟化物的快速裂解，收率好至极好。在正己烷中，与使用THF相比，Sm（HMDS）_2对CF键具有独特的增强还原能力。溶剂。

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《Chemical Communications》 |2013年第18期|1826-1828|共3页
作者
Mario Janjetovic; Annika M.Traeff; Tobias Ankner; Jenny Wettergren; Goeran Hilmersson;
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Department of Chemistry and Molecular Biology, University of Gothenburg,Kemivdgen 10, SE-412 96, Gothenburg, Sweden;

Department of Chemistry and Molecular Biology, University of Gothenburg,Kemivdgen 10, SE-412 96, Gothenburg, Sweden;

Department of Chemistry and Molecular Biology, University of Gothenburg,Kemivdgen 10, SE-412 96, Gothenburg, Sweden;

Department of Chemistry and Molecular Biology, University of Gothenburg,Kemivdgen 10, SE-412 96, Gothenburg, Sweden;

Department of Chemistry and Molecular Biology, University of Gothenburg,Kemivdgen 10, SE-412 96, Gothenburg, Sweden;

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入库时间 2022-08-17 13:18:00

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Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)_2

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