A highly luminescent and highly oxygen-sensitive Tb(Ⅲ) complex with a tris-aryloxide functionalised 1,4,7-triazacyclononane ligand

Hidetaka Nakai; Takahiro Goto; Kazuhiro Kitagawa; Kyoshiro Nonaka; Takahiro Matsumoto; Seiji Ogo

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A highly luminescent and highly oxygen-sensitive Tb(Ⅲ) complex with a tris-aryloxide functionalised 1,4,7-triazacyclononane ligand

机译：具有三芳基氧化物官能化的1,4,7-三氮杂环壬烷配体的高发光和高氧敏感性Tb（Ⅲ）配合物

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This communication presents a new terbium(Ⅲ) complex that shows the highest luminescence quantum yield among the oxygen-sensitive lanthanide complexes (Φ = 0.91 under N_2, Φ = 0.054 under air).

机译：这种交流提出了一种新的b（Ⅲ）配合物，该配合物在氧敏感性镧系元素配合物中显示出最高的发光量子产率（在N_2下Φ= 0.91，在空气下Φ= 0.054）。

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《Chemical Communications》 |2014年第99期|15737-15739|共3页
作者
Hidetaka Nakai; Takahiro Goto; Kazuhiro Kitagawa; Kyoshiro Nonaka; Takahiro Matsumoto; Seiji Ogo;
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作者单位

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan,Centre for Small Molecule Energy, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan;

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan;

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan,International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan;

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan,International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan;

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan,Centre for Small Molecule Energy, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan,International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan;

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan,Centre for Small Molecule Energy, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan,International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan;

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入库时间 2022-08-17 13:16:46

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2. Tb-III/3d-Tb-III clusters derived from a 1,4,7-triazacyclononane-based hexadentate ligand with field-induced slow magnetic relaxation and oxygen-sensitive luminescence [J] . Wen He-Rui, Zhang Jia-Li, Liang Fu-Yong, New Journal of Chemistry . 2019,第10期

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3. Structural and Photophysical Studies of Highly Stable Lanthanide Complexes of Tripodal 8-Hydroxyquinolinate Ligands Based on 1,4,7-Triazacyclononane [J] . Nonat A, Imbert D, Pecaut J, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第9期

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4. A Long-Lived, Highly Luminescent Rhenium (I) Metal-ligand Complex as a Probe of Biomolecules [C] . Felix N. Castellno, Xiang-Qun Guo, Li Li, Fluorescence Science and Technology . 2000

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A highly luminescent and highly oxygen-sensitive Tb(Ⅲ) complex with a tris-aryloxide functionalised 1,4,7-triazacyclononane ligand

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