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A high rotational barrier for physisorbed hydrogen in an fcu-metal-organic framework

机译：立方金属金属有机框架中物理吸附氢的高旋转势垒

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摘要

A combined inelastic neutron scattering (INS) and theoretical study of H_2 sorption in Y-FTZB, a recently reported metal-organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H_2. This rotational barrier for H_2 is the highest yet of reported MOF materials based on physisorption.
机译：结合非弹性中子散射（INS）和Y-FTZB（一种最近报道的具有fcu拓扑结构的金属有机框架）中H_2吸附的理论研究，发现MOF中最强的结合位点会导致高旋转壁上的旋转障碍吸附的H_2。 H_2的这种旋转势垒是基于物理吸附的迄今为止报道的MOF材料中最高的。

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  • 来源
    《Chemical Communications》 |2014年第91期|14109-14112|共4页
  • 作者

    Tony Pham; Katherine A. Forrest; Peter A. Georgiev; Wiebke Lohstroh; Dong-Xu Xue; Adam Hogan; Mohamed Eddaoudi; Brian Space; Juergen Eckert;

  • 作者单位

    Department of Chemistry, University of South Florida, 4202 East Fowler Avenue,CHE205, Tampa, FL 33620, USA;

    Department of Chemistry, University of South Florida, 4202 East Fowler Avenue,CHE205, Tampa, FL 33620, USA;

    Department of Structural Chemistry, University of Milan, 21 Via G. Venezian, I-20133 Milan, Italy,Faculty of Chemistry and Pharmacy, University of Sofia, 1 James Bourchier Blvd., Sofia 1164, Bulgaria;

    Heinz Maier-Leibnitz Zentrum (MLZ), Technische Universitaet Muenchen, Lichtenbergstrasse1, D-85748 Garching, Germany;

    Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering, 4700 King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia;

    Department of Chemistry, University of South Florida, 4202 East Fowler Avenue,CHE205, Tampa, FL 33620, USA;

    Department of Chemistry, University of South Florida, 4202 East Fowler Avenue,CHE205, Tampa, FL 33620, USA,Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering, 4700 King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia;

    Department of Chemistry, University of South Florida, 4202 East Fowler Avenue,CHE205, Tampa, FL 33620, USA;

    Department of Chemistry, University of South Florida, 4202 East Fowler Avenue,CHE205, Tampa, FL 33620, USA;

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  • 入库时间 2022-08-17 13:16:35

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