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Fluorinated microporous organic polymers: design and applications in CO_2 adsorption and conversion

机译：氟化微孔有机聚合物：CO_2吸附和转化的设计与应用

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摘要

Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO_2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(Ⅰ), and the resultant F-MOP-Ag(Ⅰ) displayed high efficiency for the reaction of CO_2 with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 ℃.
机译：设计了氟化微孔有机聚合物（F-MOPs），其CO_2吸附容量是相应的非氟MOP的两倍。将菲咯啉部分掺入F-MOPs中使其具有与Ag（Ⅰ）配位的能力，并且所得F-MOP-Ag（Ⅰ）对CO_2与炔丙醇反应形成α-亚烷基环状碳酸酯具有很高的效率。在25℃下。

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  • 来源
    《Chemical Communications》 |2014年第90期|13910-13913|共4页
  • 作者

    Zhen-Zhen Yang; Yanfei Zhao; Hongye Zhang; Bo Yu; Zhishuang Ma; Guipeng Ji; Zhimin Liu;

  • 作者单位

    Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

    Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

    Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

    Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

    Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

    Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

    Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

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  • 入库时间 2022-08-17 13:16:35

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