Isolation and characterization of [5,6]-pyrrolidino- Sc_3N@I_h-C_(80) diastereomers

Yutaka Maeda; Masato Kimura; Chihiro Ueda; Michio Yamada; Toru Kikuchi; Mitsuaki Suzuki; Wei-Wei Wang; Naomi Mizorogi; Nikolaos Karousis; Nikos Tagmatarchis; Tadashi Hasegawa; Marilyn M. Olmstead; Alan L. Balch; Shigeru Nagase; Takeshi Akasaka

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Isolation and characterization of [5,6]-pyrrolidino- Sc_3N@I_h-C_(80) diastereomers

机译：[5,6]-吡咯烷基-Sc_3N @ I_h-C_（80）非对映异构体的分离与表征

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Reactions of Sc_3N@I_h-C_(80) with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc_3N@I_h-C_(80) was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations.

机译：进行Sc_3N @ I_h-C_（80）与氮丙啶衍生物的反应，得到相应的单加合物。分离出一对[5，6]-吡咯烷基-Sc_3N @ I_h-C_（80）的非对映异构体，并通过质谱，vis-NIR吸收光谱和电化学测量进行表征。通过NMR和单晶X射线结构测定进行单加合物的结构分析。

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来源
《Chemical Communications》 |2014年第83期|12552-12555|共4页
作者
Yutaka Maeda; Masato Kimura; Chihiro Ueda; Michio Yamada; Toru Kikuchi; Mitsuaki Suzuki; Wei-Wei Wang; Naomi Mizorogi; Nikolaos Karousis; Nikos Tagmatarchis; Tadashi Hasegawa; Marilyn M. Olmstead; Alan L. Balch; Shigeru Nagase; Takeshi Akasaka;
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Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan;

Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan;

Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan;

Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan;

Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan;

Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan;

Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto, 606-8103, Japan;

Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan;

Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, Athens 11635, Greece;

Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, Athens 11635, Greece;

Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan;

Department of Chemistry, University of California at Davis, One Shields Ave, Davis, CA 95616, USA;

Department of Chemistry, University of California at Davis, One Shields Ave, Davis, CA 95616, USA;

Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto, 606-8103, Japan;

Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan, Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan, College of Materials Science and Engineering, Huazhong University of Science and Technology, 430074 Wuhan, China Foundation for Advancement of International Science, Tsukuba, Ibaraki 305-0821, Japan;

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入库时间 2022-08-17 13:16:22

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Isolation and characterization of [5,6]-pyrrolidino- Sc_3N@I_h-C_(80) diastereomers

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