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Affecting surface chirality via multicomponent adsorption of chiral and achiral molecules

机译：通过手性和非手性分子的多组分吸附影响表面手性

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摘要

Here we report on the apparent reduction in surface chirality upon co-assembling a chiral and achiral molecule into a physisorbed self-assembled monolayer at the liquid/solid interface as revealed by scanning tunneling microscopy (STM). Chiral OPV with achiral thymine gives rise to surface-confined supramolecular diastereomers.
机译：在这里，我们报道了通过扫描隧道显微镜（STM）揭示的在液体/固体界面上将手性和非手性分子共同组装成物理吸附的自组装单层表面的手性明显降低。手性OPV与非手性胸腺嘧啶产生表面受限的超分子非对映异构体。

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  • 来源
    《Chemical Communications》 |2014年第80期|11903-11906|共4页
  • 作者

    Zongxia Guo; Inge De Cat; Bernard Van Averbeke; Jianbin Lin; Guojie Wang; Hong Xu; Roberto Lazzaroni; David Beljonne; Albertus P. H. J. Schenning; Steven De Feyter;

  • 作者单位

    Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200 F, B-3001 Leuven, Belgium,CAS Key Laboratory of Bio-based Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China;

    Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200 F, B-3001 Leuven, Belgium;

    Service de Chimie des Materiaux Nouveaux, Universite de Mons, Place du Parc 20, 7000 Mons, Belgium;

    Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands;

    Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200 F, B-3001 Leuven, Belgium,School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Beijing 100083, China;

    Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200 F, B-3001 Leuven, Belgium;

    Service de Chimie des Materiaux Nouveaux, Universite de Mons, Place du Parc 20, 7000 Mons, Belgium;

    Service de Chimie des Materiaux Nouveaux, Universite de Mons, Place du Parc 20, 7000 Mons, Belgium;

    Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands,Laboratory of Functional Organic Materials, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands;

    Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200 F, B-3001 Leuven, Belgium;

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  • 入库时间 2022-08-17 13:16:24

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