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Engineering the surface of perovskite La_(0.5)Sr_(0.5)MnO_3 for catalytic activity of CO oxidation

机译:改造钙钛矿La_(0.5)Sr_(0.5)MnO_3的表面以提高CO氧化的催化活性

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摘要

A simple treatment of La_(0.5)Sr_(0.5)MnO_3 with diluted HNO_3 creates more B-sites (rich) on the terminated perovskite surface and improves its catalytic activity toward CO oxidation, and the perovskite catalyst possesses a higher ratio of Mn~(4+)/Mn~(3+) and thus enhances the O_2 adsorption capability, favourable for CO oxidation and catalytic activity.
机译:用稀释的HNO_3简单处理La_(0.5)Sr_(0.5)MnO_3在终止的钙钛矿表面上产生更多的B-位(富集)并提高其对CO氧化的催化活性,而钙钛矿催化剂具有较高的Mn〜( 4 +)/ Mn〜(3+),提高了O_2的吸附能力,有利于CO的氧化和催化活性。

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  • 来源
    《Chemical Communications》 |2014年第65期|9200-9203|共4页
  • 作者单位

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;

    Department of Basic Science, Jilin Jianzhu University, Changchun 130118, P. R. China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;

    Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey 08854, USA;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;

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  • 入库时间 2022-08-17 13:16:05

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