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首页> 外文期刊>Chemical Communications >Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer
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Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer

机译：使用基于金属卟啉的共轭微孔聚合物高效高效地捕获碘

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摘要

A new metalloporphyrin-based conjugated microporous polymer, NiP-CMP, was constructed via a homo-coupling polymerization reaction. NiP-CMP possesses a high BET surface area of over 2600 m~2 g~(-1) a large pore volume of 2.288 cm~3 g~(-1), good stability, and displays excellent guest uptake of 202 wt% in iodine vapour. We also highlight that the polymer exhibits outstanding performance for the reversible adsorption of iodine in solution.
机译：通过均偶联聚合反应构建了一种新的基于金属卟啉的共轭微孔聚合物NiP-CMP。 NiP-CMP具有超过2600 m〜2 g〜（-1）的高BET表面积，2.288 cm〜3 g〜（-1）的大孔体积，良好的稳定性，并显示出202 wt％的优异客体吸收碘蒸气。我们还强调指出，聚合物在溶液中可逆吸附碘方面表现出出色的性能。

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  • 来源
    《Chemical Communications》 |2014年第62期|8495-8498|共4页
  • 作者

    Sigen A; Yuwei Zhang; Zhongping Li; Hong Xia; Ming Xue; Xiaoming Liu; Ying Mu;

  • 作者单位

    State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, 130012, P.R. China;

    State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, 130012, P.R. China;

    State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, 130012, P.R. China;

    State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Technology, Jilin University, Changchun, 130012, P.R. China;

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P.R. China;

    State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, 130012, P.R. China;

    State Key Laboratory for Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, 130012, P.R. China;

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