Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions

Ryota Matsuoka Ryota Sakamoto* Tetsuya Kambe Kenji Takada Tetsuro Kusamoto; Hiroshi Nishihara

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Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions

机译：通过界面反应生成的一维π共轭镍双（二硫代烯）镍络合物的有序排列

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A liquid-liquid interfacial synthesis using 1,2,4,5-benzenetetrathiol and nickel(ⅱ) ions produced a thin black film of a π-conjugated polymer featuring the nickel bis(dithiolene) motif. Its ordered structure was not originally identified due to its amorphicity; however, it was observed to align regularly on a highly oriented pyrolytic graphite substrate using scanning tunnelling microscopy.

机译：使用1,2,4,5-苯四硫醇和镍（ⅱ）离子的液-液界面合成产生了具有镍双（二硫代烯）图案的π共轭聚合物的黑色薄膜。由于其无定形性，最初没有确定其有序结构。然而，使用扫描隧道显微镜观察到在高度取向的热解石墨基底上规则排列。

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《Chemical Communications》 |2014年第60期|8137-8139|共3页
作者
Ryota Matsuoka Ryota Sakamoto* Tetsuya Kambe Kenji Takada Tetsuro Kusamoto; Hiroshi Nishihara;
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Department of Chemistry, Graduate School of Science, The University of Tokyo,7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan;

Department of Chemistry, Graduate School of Science, The University of Tokyo,7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan;

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5. Studies of the solution chemistry in the oxidation reaction to produce the one-dimensional partially oxidized bis(oxalato)platinate polymers. [D] . Keller, Barbara Jo. 1995

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8. Soluble and Electroactive Nickel Bis(dithiolene) Polymers Prepared Via Metal Complexation Polymerization. [R] . Wang, F., Reynolds, J. R. 1990

机译：通过金属络合聚合制备的可溶性和电活性镍双（二硫杂环戊烯）聚合物。

Ordered alignment of a one-dimensional π-conjugated nickel bis(dithiolene) complex polymer produced via interfacial reactions

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