tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp~3)-H/C(sp~2)-H bond functionalization

Jia-Jia Cao; Tong-Hao Zhu; Shun-Yi Wang; Zheng-Yang Gu; Xiang Wang; Shun-Jun Ji

首页> 外文期刊>Chemical Communications >tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp~3)-H/C(sp~2)-H bond functionalization

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tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp~3)-H/C(sp~2)-H bond functionalization

机译：过氧苯甲酸叔丁酯（TBPB）介导的2-异氰基双芳基与1,4-二恶烷的插入：通过C（sp〜3）-H / C（sp〜2）-H键功能化有效合成6-烷基菲啶

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An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C-C bonds were formed in this reaction via a sequential C(sp~3)-H/C(sp~2)-H bond functionalization under metal-free conditions.

机译：建立了通过过氧苯甲酸叔丁酯（TBPB）介导的2-异氰基联芳基与1,4-二恶烷的插入构建6-烷基菲啶的有效方法。在该反应中，在无金属条件下，通过连续的C（sp〜3）-H / C（sp〜2）-H键官能化反应形成了两个新的C-C键。

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来源
《Chemical Communications》 |2014年第49期|6439-6442|共4页
作者
Jia-Jia Cao; Tong-Hao Zhu; Shun-Yi Wang; Zheng-Yang Gu; Xiang Wang; Shun-Jun Ji;
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Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;

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入库时间 2022-08-17 13:15:58

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tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp~3)-H/C(sp~2)-H bond functionalization

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