Simple procedure for mono- and bis-end-functionalization of regioregular poly(3-hexylthiophene)s using chalcogens

Ken Okamoto; Christine K. Luscombe

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Simple procedure for mono- and bis-end-functionalization of regioregular poly(3-hexylthiophene)s using chalcogens

机译：简单的程序，使用硫族元素基团对规则的聚（3-己基噻吩）的单端和双端功能化

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The efficient synthesis of regioregular poly(3-hexylthiophene-2,5-diyl)s (rr-P3HTs) capped with chalcogens using a simple quenching method is reported. Thiol (SH) end groups are selectively installed at the terminating end (ω-end) or at both the initiating (α-) and ω-ends using sulphur powder or triisopropylsilanethiol (TIPS-SH), respectively.

机译：报道了使用简单的淬灭方法有效合成有硫族元素覆盖的区域规则的聚（3-己基噻吩-2,5-二基）（rr-P3HTs）。分别使用硫磺粉或三异丙基甲硅烷硫醇（TIPS-SH）将硫醇（SH）端基选择性地安装在末端（ω-端）或起始（α-）和ω-端。

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《Chemical Communications》 |2014年第40期|5310-5312|共3页
作者
Ken Okamoto; Christine K. Luscombe;
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Department of Materials Science and Engineering, University of Washington, Seattle, WA, 98195-2120, USA,Molecular Engineering and Sciences Institute, University of Washington, Seattle, WA, 98195-1652, USA;

Department of Materials Science and Engineering, University of Washington, Seattle, WA, 98195-2120, USA,Molecular Engineering and Sciences Institute, University of Washington, Seattle, WA, 98195-1652, USA;

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入库时间 2022-08-17 13:15:40

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4. Synthesis, mobility, and conductivity of well-defined regioregular poly(3-hexylthiophene) and diblock copolymers of regioregular poly(3-hexylthiophene) [C] . Genevieve Sauve, Rui Zhang, Shijun Jia, Organic Field-Effect Transistors V . 2006

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6. Understanding the Intrinsic Carrier Transport in Highly Oriented Poly(3-hexylthiophene): Effect of Side Chain Regioregularity [O] . Sanyin Qu, Chen Ming, Qin Yao, 2018

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Simple procedure for mono- and bis-end-functionalization of regioregular poly(3-hexylthiophene)s using chalcogens

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