Supramolecular association behavior of a strong C_(60) receptor with conjugated pentacene and tetrathiafulvalene moieties in solution and in the solid state

Zhongmin Zhou; Yunke Qin; Wei Xu; Daoben Zhu

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Supramolecular association behavior of a strong C_(60) receptor with conjugated pentacene and tetrathiafulvalene moieties in solution and in the solid state

机译：强C_（60）受体与并五苯和四硫富瓦烯部分在溶液和固态中的超分子缔合行为

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A π-extended tetrathiafulvalene (exTTF) containing a conjugated pentacene moiety showed a large binding affinity toward C_(60) in solution. The crystal structure analysis of the cocrystal formed by this exTTF and C_(60) revealed that strong π-π interactions existed between C_(60) and naphthalene and 1,3-dithiol-2-ylidene units.

机译：含有共轭并五苯部分的π-延伸的四硫富瓦烯（exTTF）对溶液中的C_（60）表现出较大的结合亲和力。由该exTTF和C_（60）形成的共晶体的晶体结构分析表明，C_（60）与萘和1,3-二硫醇-2-亚烷基单元之间存在强的π-π相互作用。

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《Chemical Communications》 |2014年第31期|4082-4084|共3页
作者
Zhongmin Zhou; Yunke Qin; Wei Xu; Daoben Zhu;
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Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China,University of Chinese Academy of Sciences, Beijing 100049, P. R. China;

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China,University of Chinese Academy of Sciences, Beijing 100049, P. R. China;

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China;

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China;

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入库时间 2022-08-17 13:15:26

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3. Carbon Nanotubes Conjugated with Triazole‐Based Tetrathiafulvalene‐Type Receptors for C 60 60 Recognition [J] . Mateos‐Gil Jaime, Calbo Joaquín, Rodríguez‐Pérez Laura, ChemPlusChem . 2019,第6期

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Supramolecular association behavior of a strong C_(60) receptor with conjugated pentacene and tetrathiafulvalene moieties in solution and in the solid state

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