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首页> 外文期刊>Chemical Communications >The first case of an actinide polyrotaxane incorporating cucurbituril: a unique 'dragon-like' twist induced by a specific coordination pattern of uranium
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The first case of an actinide polyrotaxane incorporating cucurbituril: a unique 'dragon-like' twist induced by a specific coordination pattern of uranium

机译：结合葫芦素的incorporating系元素聚轮烷的第一种情况：铀的特定配位模式引起的独特“龙样”扭曲

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摘要

In situ assembly of a cucurbituril-based pseudorotaxane and a uranyl nitrate precursor under hydrothermal conditions affords the first actinide polyrotaxane with a unique 'dragon-like' twist, which is induced by the specific coordination pattern of uranium and stabilized by hydrogen bonding between the η~1-mode carboxylate group and adjacent methylene moieties of CB.
机译：在水热条件下基于葫芦草的假轮烷和硝酸铀酰的前体的原位组装提供了具有独特“龙样”扭曲的第一act系元素聚轮烷，这是由铀的特定配位模式引起的，并通过η之间的氢键稳定的CB的〜1-模式羧酸酯基团和相邻的亚甲基部分。

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  • 来源
    《Chemical Communications》 |2014年第27期|3612-3615|共4页
  • 作者

    Lei Mei; Qun-yan Wu; Cai-ming Liu; Yu-liang Zhao; Zhi-fang Chai; Wei-qun Shi;

  • 作者单位

    Group of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China;

    Group of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China;

    Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China;

    Group of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China;

    Group of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China,School of Radiological & Interdisciplinary Sciences, Soochow University, Suzhou, 215123, P. R. China;

    Group of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China;

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  • 入库时间 2022-08-17 13:15:13

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