The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

Qiang Chen; Shinya Tanaka; Takeshi Fujita; Luyang Chen; Taketoshi Minato; Yoshifumi lshikawa; Mingwei Chen; Naoki Asao; Yoshinori Yamamoto; Tienan Jin

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The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

机译：纳米多孔AuPd合金催化剂对共轭环烯酮的高化学选择性1,4-氢化硅烷化的协同效应

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The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.

机译：与单金属纳米多孔Au和Pd催化剂相比，纳米多孔AuPd（AuPdNPore）合金催化剂对共轭环烯酮与氢硅烷的直接1,4-氢化硅烷化反应显示出优异的化学选择性和高催化活性。 AuPdNPore的增强的催化性能主要来自纳米孔结构和AuPd合金的协同作用。

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《Chemical Communications》 |2014年第25期|3344-3346|共3页
作者
Qiang Chen; Shinya Tanaka; Takeshi Fujita; Luyang Chen; Taketoshi Minato; Yoshifumi lshikawa; Mingwei Chen; Naoki Asao; Yoshinori Yamamoto; Tienan Jin;
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WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;

WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;

WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;

WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;

Institute for International Advanced Interdisciplinary Research (IIAIR), International Advanced Research and Education Organization, Tohoku University, Sendai, 980-8578, Japan;

WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;

WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;

WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;

WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan ,State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;

WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan;

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入库时间 2022-08-17 13:15:12

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1. Chiral bidentate bis(N-heterocyclic carbene)-based palladium complexes bearing carboxylate ligands: Highly effective catalysts for the enantioselective conjugate addition of arylboronic acids to cyclic enones [J] . Zhang T, Shi M Chemistry: A European journal . 2008,第12期

机译：带有羧酸盐配体的手性双齿双（N-杂环卡宾）基钯配合物：高效芳烃对环烯酮的对映选择性共轭加成催化剂
2. Highly enantioselective copper-catalyzed 1,4-conjugate addition of diethylzinc to cyclic enones and alpha,beta-unsaturated lactones [J] . Liang L, Yan M, Li YM, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2004,第16期

机译：二乙基锌对环烯酮和α，β-不饱和内酯的高对映选择性铜催化1,4-共轭加成
3. Simple Palladacyclic and Platinacyclic Catalysts for the 1,4-Conjugate Addition of Arylboronic Acids and Arylsiloxanes to Enones [J] . Robin B. Bedford, Michael Betham, Jonathan P. H. Charmant Organometallics . 2007,第25期

机译：简单的Palladacyclic和Platincyclic催化剂，用于将1,4-共轭芳基硼酸和芳基硅氧烷加成烯酮
4. Asymmetric 1,4-Addition of Alkenylzirconocenes to Conjugated Enones Catalyzed by Chiral Rhodium Complexes [C] . Takashi Sato, Shuichi Oi, Yoshio Inoue Symposium on Organometallic Chemistry . 2004

机译：不对称的1,4-加入链烯基锆，并通过手性铑配合物催化的缀合肿瘤
5. I. Stereochemistry of cyclopropane formation involving group (IV) organometallic complexes. II. Slower stoichiometric and faster catalytic reduction of aldehydes by the PPh(3) substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph(2)-3,4-Tol(2)(eta(5)-C(4)COH)]Ru(CO)(PPh(3))H: A highly chemoselective catalyst for hydrogenation of aldehydes over ketones. [D] . Strotman, Neil Adham. 2005

机译：I.涉及（IV）族有机金属配合物的环丙烷形成的立体化学。二。由PPh（3）取代的羟基环戊二烯基氢化钌[2,5-Ph（2）-3,4-Tol（2）（eta（5）-C（4）COH）] Ru的化学计量较慢和较快的醛催化还原（CO）（PPh（3））H：一种高度化学选择性的催化剂，用于醛在酮上的氢化。
6. Palygorskite Supported AuPd Alloy Nanoparticles as Efficient Nano-Catalysts for the Reduction of Nitroarenes and Dyes at Room Temperature [O] . Jun Xu, Shengli Guo, Lei Jia, 2018

机译：坡缕石负载的AuPd合金纳米颗粒作为在室温下还原硝基芳烃和染料的高效纳米催化剂
7. Highly enantioselective copper-catalyzed 1,4-conjugate addition of diethylzinc to cyclic enones and α,β-unsaturated lactones [O] . Liang L, Yan M, Li YM, 2004

机译：高对映选择性铜催化的二乙基锌向环烯酮和α，β-不饱和内酯的1,4-共轭加成

The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

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