Observation of allylic rearrangement in water-rich reaction

Yuan-Chao Pang; Xiufang Hou; Lei Qin; Chao Wu; Wei Xue; Yan-Zhen Zheng; Zhiping Zheng; Xiao-Ming Chen

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Observation of allylic rearrangement in water-rich reaction

机译：富水反应中烯丙基重排的观察

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摘要

Allylic rearrangement or the migration of a double bond from its original position in the carbon skeleton to an adjacent site was observed when 3,4,5,6-tetrahydrophthalate was hydrolyzed in a basic solution and in the presence of Co(Ⅱ) and Mn(Ⅱ) under hydrothermal conditions.

机译：当3,4,5,6-四氢邻苯二甲酸酯在碱性溶液中并在Co（Ⅱ）和Mn存在下进行水解时，观察到烯丙基重排或双键从其在碳骨架中的原始位置迁移到相邻位置。（Ⅱ）在水热条件下。

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《Chemical Communications》 |2014年第22期|2910-2912|共3页
作者
Yuan-Chao Pang; Xiufang Hou; Lei Qin; Chao Wu; Wei Xue; Yan-Zhen Zheng; Zhiping Zheng; Xiao-Ming Chen;
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Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China;

Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China;

Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China;

Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China;

School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China;

Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China;

Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China;

School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China;

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入库时间 2022-08-17 13:15:17

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1. Ab initio study and NBO analysis of the allylic rearrangements (hetero Claisen and Cope rearrangements) and decarboxylation reactions (retro carbonyl ene reaction) of allylformate and allyldithioformate [J] . Nori-Shargh D, Shiroudi A, Oliaey AR, Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems . 2007,第1a3期

机译：从头进行研究和NBO分析烯丙基甲酸酯和烯丙基二硫代甲酸酯的烯丙基重排（杂化Claisen和Cope重排）和脱羧反应（复古羰基烯反应）
2. Preparation of Rearranged Allylic Isocyanates from the Reaction of Allylic Alcohols with 1-Cyano-4-dimethylaminopyridinium Bromide [J] . Baidilov Daler, Makarova Mariia, Rycek Lukas, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2018,第23期

机译：用1-氰基-4-二甲基氨基吡啶鎓丙葡萄醇的烯丙基醇反应重新制备重排烯丙基异氰酸酯
3. New three-step domino reaction, "thiophilic addition-beta-elimination of fluoride-[3,3] sigmatropic rearrangement": Synthesis of alpha-allylic and alpha,alpha-bis(allylic) alpha-trifluoromethyl dithioesters [J] . Grellepois F, Timoshenko VM, Shermolovich YG, Organic letters . 2006,第19期

机译：新的三步多米诺反应，“氟的硫亲加成-消除-[3,3]σ重排”：合成α-烯丙基和α，α-双（烯丙基）α-三氟甲基二硫代酯
4. Enantioselective Reactions of Bicyclic Allylic Compounds Based on Desymmetrization of a Symmetrical Allylic Ligand Using Chiral Palladium Complexes. [C] . Ryohei Ogawa, Yusuke Shigemori, Koichi Uehara Symposium on Organometallic Chemistry . 2006

机译：双环烯丙基化合物基于使用手性钯配合物的对称烯丙基配体的脱水化合物的映选择性反应。
5. The synthesis and reactivity of allylic alcohols and their derivatives: The synthesis of (Z)-3beta,16alpha-dihydroxy-5,17(20)-pregnadiene 3-pivaloate; the Mitsunobu reaction of 2-cyclohexenols; the europium(III) -catalyzed rearrangement of allylic methoxyacetates. [D] . Shull, Brian Keith. 1991

机译：烯丙醇及其衍生物的合成和反应性：（Z）-3beta，16alpha-dihydroxy-5,17（20）-pregnadiene 3-pivaloate的合成； 2-环己醇的Mitsunobu反应；（（III）催化烯丙基甲氧基乙酸酯的重排。
6. Enantiospecific Synthesis of ortho‐Substituted 11‐Diarylalkanes by a 12‐Metalate Rearrangement/anti‐SN2′ Elimination/Rearomatizing Allylic Suzuki–Miyaura Reaction Sequence [O] . Dr. Belén Rubial, Dr. Beatrice S. L. Collins, Dr. Raphael Bigler, -1

机译：通过12-金属重排/消除-SN2消除/重新芳构化铃木-宫浦反应序列对位取代的11-二芳基烷烃的对映体合成
7. New Three-Step Domino Reaction, “Thiophilic Addition—β-Elimination of Fluoride—3,3 Sigmatropic Rearrangement”: Synthesis of α-Allylic and α,α-Bis(allylic) α-Trifluoromethyl Dithioesters. [O] . Fabienne Grellepois, Vadim M. Timoshenko, Yuriy G. Shermolovich, 2007

机译：新的三步多米诺反应，“硫酸加法 - 消除氟化物 - 3,3 Sigmatropic重排”：合成α-烯丙基和α，α-BIS（烯丙基）α-三氟甲基二硫代甾体。
8. Reaction of Allylic and Benzylic Methyl Ethers with Sodium and Trimethylchlorosilane. Evidence for the Intermediacy of Allylic Radicals and Anions [R] . Tzeng, D., Weber, W. P. 1980

机译：烯丙基和苄基甲基醚与钠和三甲基氯硅烷的反应。烯丙基自由基和阴离子的中间性证据

Observation of allylic rearrangement in water-rich reaction

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