Silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids

Wei-Ming Zhao; Xiao-Lan Chen; Jin-Wei Yuan; Ling-Bo Qu; Li-Kun Duan; Yu-Fen Zhao

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Silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids

机译：银催化苯并噻唑与羧酸的直接羧化C2-烷基化

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摘要

A novel and efficient silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids for the synthesis of 2-alkyl benzothiazoles was developed.

机译：开发了一种新颖高效的银催化的苯并噻唑与羧酸的脱羧直接C2-烷基化反应，以合成2-烷基苯并噻唑。

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来源
《Chemical Communications》 |2014年第16期|2018-2020|共3页
作者
Wei-Ming Zhao; Xiao-Lan Chen; Jin-Wei Yuan; Ling-Bo Qu; Li-Kun Duan; Yu-Fen Zhao;
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作者单位

College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450052, China;

College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450052, China;

Chemistry and Chemical Engineering School, Henan University of Technology, Zhengzhou, 450001, China;

Chemistry and Chemical Engineering School, Henan University of Technology, Zhengzhou, 450001, China;

College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450052, China;

College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450052, China,Department of Chemistry, Xiamen University, Xiamen, 361005, China;

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入库时间 2022-08-17 13:15:08

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1. Visible-light induced decarboxylative C2-alkylation of benzothiazoles with carboxylic acids under metal-free conditions [J] . Wang Bin, Li Pinhua, Miao Tao, Organic & biomolecular chemistry . 2019,第1期

机译：在无金属条件下可见光诱导的苯并噻唑与羧酸的脱羧C2-烷基化
2. Cobalt(III)-Catalyzed C-H Activation: A Secondary Amide Directed Decarboxylative Functionalization of Alkynyl Carboxylic Acids Wherein Amide NH-group Remains Unreactive (vol 360, pg 1370, 2018) [J] . Advanced synthesis & catalysis . 2020,第8期

机译：钴（III） - 催化C-H活化：丙二酰羧酸的二次酰胺指向脱羧官能化，其中酰胺NH-基团保持不变（Vol 360，PG 1370,2018）
3. Retraction: Palladium‐Catalyzed Decarboxylative Selective Acylation of 4H‐Benzo[d][1,3]oxazin‐4‐one Derivatives with α‐Oxo Carboxylic Acids via Preferential Cyclic Imine‐N‐Directed Aryl C?H Activation [J] . Advanced synthesis & catalysis . 2020,第3期

机译：收缩：钯 - 催化的脱羧选择性4h-苯并[1,3]的脱羧-4-一种衍生物，通过优先循环酰胺-N-指定向芳基-H激活α-氧代羧酸
4. Direct Conversion of Esters, Lactones, and Carboxylic Acids to Oxazolines Catalyzed by a Tetranuclear Zinc Cluster [C] . Takanori Iwasaki, Takashi Ohshima, Kazushi Mashima Symposium on Organometallic Chemistry . 2006

机译：将酯，内酯和羧酸直接转化为由四核锌簇催化的恶唑啉植物
5. Exploration of alpha-Diazocarbonyl Compounds for Transition-Metal Catalyzed Carbon-Carbon Bond Formations. Development of Palladium-Catalyzed Stereoselective Synthesis of Trisubstituted Alkenes and the Synthesis of Quaternary alpha,alpha-Heterodiaryl Carboxylic Acids by Rhodium-Catalyzed Multi-Component Coupling Reactions. [D] . Tsoi, Yuk Tai. 2012

机译：探索用于过渡金属催化的碳-碳键形成的α-重氮羰基化合物。铑催化的多组分偶合反应在钯催化的立体选择性合成三取代的烯烃上的发展和季铵的α，α-杂二芳基羧酸的合成。
6. Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process [O] . Jiancan Zhao, Hong Fang, Jianlin Han, 2013

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7. Silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids [O] . Zhao Wei-Ming, Chen Xiao-Lan, Yuan Jin-Wei, 2014

机译：银催化苯并噻唑与羧酸的直接羧化C2-烷基化

Silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids

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