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首页> 外文期刊>Chemical Communications >Co-assembly of a three-dimensional open framework sulfide with a novel linkage between an oxygen-encapsulated T3 cluster and a supertetrahedral T2 cluster
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Co-assembly of a three-dimensional open framework sulfide with a novel linkage between an oxygen-encapsulated T3 cluster and a supertetrahedral T2 cluster

机译：三维封装的框架硫化物的共组装，其中氧包裹的T3团簇和超四面体T2团簇之间具有新颖的连接

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摘要

Solvothermal reactions of S, Ga and Sn using c/s-2,6-dimethyl-morpholine (DMMP) as an organic template, in the presence of a trace amount of H_2O at 180 ℃, generated microporous [C_6H_(14)NOl_(14.4)[Ga_(6.40)Sn_(21.60)S_(52)O_8] material composed of hybrid T2 and T3 supertetrahedral clusters with a PtS type topology.
机译：以c / s-2,6-二甲基吗啉（DMMP）为有机模板，在痕量H_2O存在下于180℃进行S，Ga和Sn的溶剂热反应，生成微孔[C_6H_（14）NOl_（ 14.4）[Ga_（6.40）Sn_（21.60）S_（52）O_8]材料由具有PtS型拓扑的混合T2和T3超四面体簇组成。

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  • 来源
    《Chemical Communications》 |2014年第7期|796-798|共3页
  • 作者

    Xiaohui Han; Zhenqing Wang; Dan Liu; Jin Xu; Yongxin Liu; Cheng Wang;

  • 作者单位

    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, P.R. China,The University of Chinese Academy of Sciences, Beijing 100049, P.R. China;

    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, P.R. China;

    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, P.R. China;

    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, P.R. China;

    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, P.R. China,The University of Chinese Academy of Sciences, Beijing 100049, P.R. China;

    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, P.R. China;

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