Base-free hydrogen generation from methanol using a bi-catalytic system

Angele Monney; Enrico Barsch; Peter Sponholz; Henrik Junge; Ralf Ludwig; Matthias Beller

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Base-free hydrogen generation from methanol using a bi-catalytic system

机译：使用双催化系统由甲醇产生无碱氢

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A bi-catalytic system, in which Ru-MACHO-BH and Ru(H)_2(dppe)_2 interact in a synergistic manner, was developed for the base-free dehydrogenation of methanol. A total TON > 4200 was obtained with only trace amounts of CO contamination (<8 ppm) in the produced gas.

机译：建立了Ru-MACHO-BH和Ru（H）_2（dppe）_2协同作用的双催化体系，用于甲醇的无碱脱氢。获得的总TON> 4200，而产出气中仅存在痕量的CO污染（<8 ppm）。

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《Chemical Communications》 |2014年第6期|707-709|共3页
作者
Angele Monney; Enrico Barsch; Peter Sponholz; Henrik Junge; Ralf Ludwig; Matthias Beller;
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Leibniz-lnstitut fuer Katalyse e. V. and der Universitaet Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany;

Leibniz-lnstitut fuer Katalyse e. V. and der Universitaet Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany;

Leibniz-lnstitut fuer Katalyse e. V. and der Universitaet Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany;

Leibniz-lnstitut fuer Katalyse e. V. and der Universitaet Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany;

Leibniz-lnstitut fuer Katalyse e. V. and der Universitaet Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany;

Leibniz-lnstitut fuer Katalyse e. V. and der Universitaet Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany;

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入库时间 2022-08-17 13:14:56

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4. Hydrogen generation for fuel-cell power systems by high-pressure catalytic methanol-steam reforming [C] . Peppley, B.A., Amphlett, Energy Conversion Engineering Conference, 1997. IECEC-97., Proceedings of the 32nd Intersociety . 1997

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机译：二氧化碳氢化对甲酸，具有极其有效的无碱性均匀催化系统

Base-free hydrogen generation from methanol using a bi-catalytic system

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