Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ionf

Pandur Venkatesan Balaji; Srinivasan Chandrasekaran

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Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ionf

机译：溴离子介导的乙烯基芳烃的立体选择性双键双官能化

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An anti-Markovnikov geminal oxyamination of styrenyl alkenes in an intermolecutar fashion using the umpolung strategy mediated by the bromonium ion is reported. Isotope labeling studies confirm the migration of the phenyl group in the semipinacol rearrangement.

机译：报道了使用溴离子介导的聚对苯二酚策略以分子间方式对苯乙烯基烯烃进行抗马尔科夫尼科夫双胺氧化。同位素标记研究证实了在频哪醇重排中苯基的迁移。

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《Chemical Communications》 |2014年第1期|70-72|共3页
作者
Pandur Venkatesan Balaji; Srinivasan Chandrasekaran;
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作者单位

Department of Organic Chemistry, Indian Institute of Science, Bangalore-560012, India;

Department of Organic Chemistry, Indian Institute of Science, Bangalore-560012, India;

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入库时间 2022-08-17 13:14:45

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机译：通过乙烯基芳烃的双双官能化或氮丙啶本身的串联开环/闭环反应将氮丙啶转化为恶唑烷
2. Stereoselective Anti-Markovnikov Geminal Diamination and Dioxygenation of Vinylarenes Mediated by the Bromonium Ion [J] . Balaji Pandur Venkatesan, Chandrasekaran Srinivasan European journal of organic chemistry . 2016,第14期

机译：溴离子介导的乙烯基芳烃的立体选择性抗马尔科夫尼科夫双金属化和双加氧反应
3. Cu2O Nanocubes Catalyzed Difunctionalization Reaction of Vinyl Arenes with Cyclic Ethers [J] . Jee Young Kim, Ji Chan Park, Hyunjoon Song Bulletin of the Korean Chemical Society . 2010,第12期

机译：Cu2O纳米立方体催化乙烯基芳烃与环醚的双官能化反应
4. Stereoselective Synthesis of Quaternary,α-Vinyl Amino Acids and Their α-(2'Z-Fluoro)vinyl Congeners: Promising Candidates for PLP Enzyme Inactivation [C] . David B. Berkowitz, Kannan R. Karukurichi, Roberto de la Salud-Bea, Asymmetric synthesis and application of α-amino acids . 2007

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5. New Palladium- and Gold-Catalyzed Alkene and Alkyne Difunctionalization Reactions for the Efficient, Stereoselective Synthesis of Azabicycles and β-Alkoxy Ketones [D] . Schultz, Danielle M 2012

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6. Stereoselective Synthesis of trans-Olefins by the Copper-Mediated SN2′ Reaction of Vinyl Oxazines with Grignard Reagents. Asymmetric Synthesis of D-threo-Sphingosines [O] . Om V. Singh, Hyunsoo Han -1

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7. Beneficial Effect of a Secondary Ligand on the Catalytic Difunctionalization of Vinyl Arenes with Boron and CO 2 [O] . Trina M. Perrone, Amy S. Gregory, Steven W. Knowlden, 2019

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Stereoselective geminal difunctionalization of vinyl arenes mediated by the bromonium ionf

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