A new reaction: lead(Ⅳ) acetate-mediated oxidative fragmentation of homoallylic alcohols

Marcelo D. Preite; Mauricio A. Cuellar

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A new reaction: lead(Ⅳ) acetate-mediated oxidative fragmentation of homoallylic alcohols

机译：一种新的反应：乙酸铅（Ⅳ）介导的均烯丙醇的氧化裂解

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摘要

Treatment of a homoallylic alcohol with lead(Ⅳ) acetate in refluxing benzene for 2 hours results in an oxidative cleavage to give a carbonyl compound and an allylic acetate with high yield.

机译：用乙酸铅（Ⅳ）在回流的苯中处理均烯丙基醇2小时导致氧化裂解，以高收率得到羰基化合物和乙酸烯丙酯。

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来源
《Chemical Communications》 |2004年第17期|p.1970-1971|共2页
作者
Marcelo D. Preite; Mauricio A. Cuellar;
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作者单位

Departamento de Quimica Organica, Facultad de Quimica, Pontificia Universidad Catolica de Chile, Vicuna Mackenna 4860, Casilla 306, Correo-22, Santiago, Chile;

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正文语种 eng
中图分类化学;
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入库时间 2022-08-17 13:33:17

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1. Oxidation of tertiary homoallylic alcohols by thallium trinitrate: fragmentation vs. ring contraction [J] . Helena M. C. Ferraz, Leonardo S. Santos, Luiz F. Silva Jr., Journal of the Brazilian Chemical Society . 2006,第5期

机译：三硝酸th氧化叔均丙醇：断裂与环收缩
2. Oxidation of tertiary homoallylic alcohols by thallium trinitrate: Fragmentation vs. ring contraction [J] . Silva LF, Quintiliano SAP, Ferraz HMC, Journal of the Brazilian Chemical Society . 2006,第5期

机译：三硝酸th氧化叔均丙醇：断裂与环收缩
3. Cu-catalyzed cross-coupling reactions of vinyl epoxide with organoboron compounds: access to homoallylic alcohols [J] . Lu Xiao-Yu, Li Jin-Song, Wang Jin-Yu, RSC Advances . 2018,第72期

机译：用有机硼化合物的乙烯基环氧化物的Cu催化的交联反应：获得同源醇
4. Stereoselective Synthesis of δ-Silyl-Substituted anti-Homoallylic Alcohols Using Palladium-Catalyzed Three-Component Reaction [C] . MURAKAMI Miki, HORINO Yoshikazu, ABE Hitoshi 日本化学会春季年会講演予稿集 . 2018

机译：使用钯催化的三组分反应的δ-甲硅烷基取代的抗官能醇的立体选择性合成
5. Alkoxy accelerated beta-fragmentations of alcohols and lactols with lead tetraacetate and copper(II)acetate: Study of the regioselectivity of chromium-mediated [6+4] cycloadditions using thiepin-1,1-dioxide and application to the synthesis of calamenene sesquiterpenes. [D] . Payen, Anne Jeanne. 2002

机译：用四乙酸铅和乙酸铜（II）的烷氧基促进醇和乳醇的β片段断裂：使用噻吩-1,1-二氧化物对铬介导的[6 + 4]环加成反应的区域选择性进行研究，并将其应用于of草烯倍半萜的合成。
6. An Investigation of the Reactions of Substituted Homoallylic Alcohols with Various Oxidation Reagents [O] . S. Servi, A. Acar 2002

机译：取代的均丙醇与各种氧化试剂反应的研究
7. Oxidation of tertiary homoallylic alcohols by thallium trinitrate: fragmentation vs. ring contraction [O] . Silva Jr., Luiz F., Quintiliano, Samir A. P., Ferraz, Helena M. C., 2015

机译：三硝酸th氧化叔均丙醇：断裂与环收缩
8. Selective electrocatalysis of anodic oxygen-transfer reactions at chemically modified, thin-film lead dioxide electrodes. [R] . Chang, H. 1990

机译：在化学改性的薄膜二氧化铅电极上进行阳极氧转移反应的选择性电催化。

A new reaction: lead(Ⅳ) acetate-mediated oxidative fragmentation of homoallylic alcohols

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