Template-assisted self assembly of two lipophilic polyion aggregates derived from sodium tetraphenyl imidodiphosphinate-complexes containing sodium ions in four different coordination environments

摘要

The molecular structures of two lipophilic polyion aggregates derived from tetraphenyl imidodiphosphinate are described: [Na( crown ether)]{MNa2[Ph2P(O) NP(O) Ph-2](4)} with crown ether = 15-crown-5 for 1 and benzo-15-crown-5 for 2 ( M = Na+ for 1 and Na(H2O)(+) for 2).