Gauche and staggered forms of diethylamine in solvates of 1,5-dichloro-cis-9,10-diethynyl-9,10-dihydroanthracene-9,10-diol. A case of conformational pseudopolymorphism?

摘要

Diethylamine has been trapped in its less stable gauche conformation in a solvate of the title diol; the staggered conformation, which is ca. 4 kJ mol~(-1) more stable, is found in another solvate of the same host.