A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)_2(H_2O)_2](SO_4)·7H_2O[bix = 1,4-bis(imidazol-1-ylmethyl)benzene]

Lucia Carlucci; Gianfranco Ciani; Davide M. Proserpio

首页> 外文期刊>Chemical Communications >A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)_2(H_2O)_2](SO_4)·7H_2O[bix = 1,4-bis(imidazol-1-ylmethyl)benzene]

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A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)_2(H_2O)_2](SO_4)·7H_2O[bix = 1,4-bis(imidazol-1-ylmethyl)benzene]

机译：[Co（bix）_2（H_2O）_2]（SO_4）·7H_2O [bix = 1,4-bis（imidazol）的纳米孔结构中涉及一维环的链状连接到三维网络的新型纠缠-1-基甲基）苯]

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Co~Ⅱ sulfate reacts with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) to yield the coordination network [Co(bix)_2(H_2O)_2](SO_4)·7H_2O, containing polymeric ribbons of rings which penetrate and catenate a 3D single frame of the CdSO_4 topology, to produce an open-channel entangled architecture with nanoporous behaviour.

机译：硫酸Co〜Ⅱ与柔性配体1,4-双（咪唑-1-基甲基）苯（bix）反应，生成配位带[Co（bix）_2（H_2O）_2]（SO_4）·7H_2O的配位网络环穿透并连接CdSO_4拓扑的3D单帧，以生成具有纳米孔行为的明通道纠缠架构。

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来源
《Chemical Communications》 |2004年第4期|p.380-381|共2页
作者
Lucia Carlucci; Gianfranco Ciani; Davide M. Proserpio;
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作者单位

Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Via G. Venezian 21, 20133 Milano, Italy;

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正文语种 eng
中图分类化学;
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1. Syntheses and structures of four d(10) metal-organic frameworks assembled with aromatic polycarboxylate and bix [bix=1,4-bis(imidazol-1-ylmethyl)benzene] [J] . Wen LL, Li YZ, Lu ZD, Crystal growth & design . 2006,第2期

机译：芳族聚羧酸盐和bix [bix = 1,4-双（咪唑-1-基甲基）苯]组装的四个d（10）金属-有机骨架的合成和结构。
2. An Infinite 2D Polyrotaxane Network in Ag_2(bix)_3(NO_3)_2 (bix = 1,4-Bis(imidazol-1-ylmethyl)benzene) [J] . Bernard F. Hoskins, Richard Robson, Damian A. Slizys Journal of the American Chemical Society . 1997,第12期

机译：Ag_2（bix）_3（NO_3）_2（bix = 1,4-双（咪唑-1-基甲基）苯）中的无限二维聚轮烷网络
3. Synthesis, Crystal Structure, and Characterization of One 1D Complex in Ni2+/H4L/p-Bix System (H4L = Methylenediisophthalic Acid, p-Bix=1,4-Bis(Imidazol-1-Ylmethyl)-Benzene) [J] . Duan X. Y. Russian Journal of Coordination Chemistry . 2018,第1期

机译：Ni2 + / H4L / P-Bix系统中1d络合物的合成，晶体结构和表征（H4L =甲基二苯甲酸，P-BIX = 1,4-双（Imidazol-1-基甲基） - 苯））
4. Syntheses and Structures of Four d10 Metal-Organic Frameworks Assembled with Aromatic Polycarboxylate and bix bix = 1, 4-Bis(imidazol-1-ylmethyl)benzene [O] . -1

机译：用芳族多元羧酸盐和Bix组装的四个D10金属 - 有机框架的合成和结构Bix = 1,4-双（Imidazol-1-基甲基）苯

A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)_2(H_2O)_2](SO_4)·7H_2O[bix = 1,4-bis(imidazol-1-ylmethyl)benzene]

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