An outer-sphere ligand for uranyl carbonate

Anthony R. Prudden; Nathan R. Lien; Jason R. Telford

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An outer-sphere ligand for uranyl carbonate

机译：碳酸铀酰的外球配体

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摘要

A novel supramolecular host for the uranyl carbonate complex has been designed and synthesized. The modified cyclodextrin host binds uranyl carbonate in water with a stability of 253 M~(-1).

机译：设计和合成了一种新型的铀酰碳酸酯配合物的超分子宿主。修饰后的环糊精主体以253 M〜（-1）的稳定性结合碳酸铀酰。

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来源
《Chemical Communications》 |2004年第2期|p.172-173|共2页
作者
Anthony R. Prudden; Nathan R. Lien; Jason R. Telford;
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作者单位

Department of Chemistry, University of Iowa, Iowa City, IA, USA 52242-1294;

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正文语种 eng
中图分类化学;
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1. Production of high quality ammonium uranyl carbonate from 'uranyl nitrate + carbonate' precursor solution [J] . Progress in Nuclear Energy . 2020,第Apra期

机译：由“硝酸铀酰+碳酸酯”前体溶液生产高质量碳酸铀酰铵
2. Uranyl Carbonate Complexes in Aqueous Solution and Their Ligand NMR Chemical Shifts and O-17 Quadrupolar Relaxation Studied by ab Initio Molecular Dynamics [J] . Marchenko Alex, Truflandier Lionel A., Autschbach Jochen Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2017,第13期

机译：水溶液中的碳酸铀酯和它们的配体NMR化学位移和AB Initio分子动力学研究的o-17 Quadrupolar弛豫
3. Investigation of ligand exchange reactions in aqueous uranyl carbonate complexes using computational approaches [J] . Slimane Doudou, Krishnamoorthy Arumugam, David J. Vaughan Physical chemistry chemical physics: PCCP . 2011,第23期

机译：使用计算方法研究碳酸双氧铀水溶液中的配体交换反应
4. Outer-Sphere Coordination of Uranyl Carbonate by Modified Cyclodextrins: Implications for Speciation and Remediation [C] . Jason R. Telford Symposium on Nanotechnology and the Environment: Applications and Implications . 2005

机译：通过改性环糊精的碳酸铀酯的外球形配制：对形态和修复的影响
5. Expanding the Frontiers of f-Element Coordination Chemistry: New Routes to Lanthanide Ligand Multiple Bonds, High Valent Lanthanides, and Trans/Cis Isomerization and Functionalization of the Uranyl Ion [D] . Assefa, Mikiyas K. 2020

机译：扩大F元素协调化学的前沿：新的镧系元素配体多元键，高价值镧系元素和反式/顺式异构化和铀酰离子的官能化
6. Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active donor-expanded dipyrrin [O] . James R. Pankhurst, Nicola L. Bell, Markus Zegke, 2017

机译：氧化还原活性供体扩展的双吡啶支持的铀酰的内层和外层还原
7. Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin [O] . Pankhurst, James R., Bell, Nicola L., Zegke, Markus, 2017

机译：由氧化还原活性的，供体扩展的二苯乙炔支持的铀酰内球与外球的还原

An outer-sphere ligand for uranyl carbonate

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