Relative importance of hydrogen bonding and coordinating groups in modulating the zinc-water acidity

Juan C. Mareque-Rivas; Ravi Prabaharan; Rafael Torres Martin de Rosales

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Relative importance of hydrogen bonding and coordinating groups in modulating the zinc-water acidity

机译：氢键和配位基团在调节锌水酸度中的相对重要性

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The presence of second-sphere -NH_2 groups in the proximity of a zinc(Ⅱ)-bound water molecule enhances its acidity by ca. 2 pK_a units.

机译：在锌（Ⅱ）结合的水分子附近存在第二个球-NH_2基团，其酸度提高了约。 2个pK_a单位。

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《Chemical Communications》 |2004年第1期|p.76-77|共2页
作者
Juan C. Mareque-Rivas; Ravi Prabaharan; Rafael Torres Martin de Rosales;
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School of Chemistry, The University of Edinburgh, King's Buildings, West Mains Road, Edinburgh, U.K EH9 3JJ;

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正文语种 eng
中图分类化学;
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入库时间 2022-08-17 13:33:01

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Relative importance of hydrogen bonding and coordinating groups in modulating the zinc-water acidity

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